The present invention is directed to an article having at least one surface coated with electrostatically flocked material. The flock material used is one or more fibers, preferably synthetic fibers. When electrostatically flocked onto the article surface, the flock material is oriented, thus providing a silky smooth feel to the surface. The articles may include, for example, elastic articles such as rubber gloves, elastic medical drapes or wraps, elastic orthopedic supports/braces and clothing. The present invention also provides a process and apparatus for electrostatically flocking material onto an article.