发明授权
- 专利标题: Porous 4 group metal oxide and method for preparation thereof
- 专利标题(中): 多孔4族金属氧化物及其制备方法
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申请号: US10484846申请日: 2002-01-15
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公开(公告)号: US07943115B2公开(公告)日: 2011-05-17
- 发明人: Shinichi Inoue , Hidehiko Kudou , Akihiro Mutou , Tateo Ono , Toshiji Makabe , Toru Takatsuka , Hisashi Nomura
- 申请人: Shinichi Inoue , Hidehiko Kudou , Akihiro Mutou , Tateo Ono , Toshiji Makabe , Toru Takatsuka , Hisashi Nomura
- 申请人地址: JP Yokohama-shi
- 专利权人: Chiyoda Corporation
- 当前专利权人: Chiyoda Corporation
- 当前专利权人地址: JP Yokohama-shi
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: JP2001-227076 20010727; JP2001-333799 20011031; JP2001-333800 20011031
- 国际申请: PCT/JP02/00200 WO 20020115
- 国际公布: WO03/011762 WO 20030213
- 主分类号: C01G23/047
- IPC分类号: C01G23/047
摘要:
This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m2/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree. This invention further relates to a porous 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by application of a pH swing operation is characterized by a large specific surface area, excellent heat stability, high dispersion of a catalyst metal and a controlled and sharp pore distribution and is useful for a catalyst or a catalyst carrier of excellent reaction selectivity.
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