公开(公告)号：US07943115B2

公开(公告)日：2011-05-17

申请号：US10484846

申请日：2002-01-15

申请人： Shinichi Inoue ,  Hidehiko Kudou ,  Akihiro Mutou ,  Tateo Ono ,  Toshiji Makabe ,  Toru Takatsuka ,  Hisashi Nomura

发明人： Shinichi Inoue ,  Hidehiko Kudou ,  Akihiro Mutou ,  Tateo Ono ,  Toshiji Makabe ,  Toru Takatsuka ,  Hisashi Nomura

IPC分类号： C01G23/047

CPC分类号： B01J21/063 ,  B01J21/06 ,  B01J21/066 ,  B01J23/28 ,  B01J23/85 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J27/188 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/036 ,  C01G23/04 ,  C01G23/0536 ,  C01G25/02 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/17 ,  C01P2006/21 ,  C01P2006/82 ,  C10G45/08

摘要： This invention relates to a 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by adding a particle growth inhibiter to a hydrosol a hydrogel or a dried product of a hydrous 4 group metal oxide represented by MO(2-x)(OH)2x (wherein M denotes a 4 group metal and x is a number greater than 0.1 or x>0.1) followed by drying and calcining has a specific surface area of 80 m2/g or more, a pore volume of 0.2 ml/g or more and a pore sharpness degree of 50% or more and excellent heat stability and is useful for a catalyst or a catalyst carrier in which a catalyst metal is dispersed to a high degree. This invention further relates to a porous 4 group metal oxide and to a method for preparation thereof and the 4 group metal oxide prepared by application of a pH swing operation is characterized by a large specific surface area, excellent heat stability, high dispersion of a catalyst metal and a controlled and sharp pore distribution and is useful for a catalyst or a catalyst carrier of excellent reaction selectivity.

摘要翻译： 本发明涉及一种4组金属氧化物及其制备方法以及通过向水溶胶中添加颗粒生长抑制剂而制备的4组金属氧化物，所述水凝胶或由MO（2）表示的含水4族金属氧化物的干燥产物 -x）（OH）2x（其中M表示4组金属，x是大于0.1或x> 0.1的数），随后干燥和煅烧的比表面积为80m 2 / g以上，孔体积 0.2ml / g以上，孔锐度为50％以上，热稳定性优异，可用于高催化剂金属分散的催化剂或催化剂载体。 本发明还涉及一种多孔4族金属氧化物及其制备方法，通过应用pH挥发操作制备的4组金属氧化物的特征在于具有大比表面积，优异的热稳定性，催化剂的高分散性 金属和可控且尖锐的孔分布，并且可用于具有优异反应选择性的催化剂或催化剂载体。

公开(公告)号：US07691781B2

公开(公告)日：2010-04-06

申请号：US10584453

申请日：2003-12-25

申请人： Shinichi Inoue ,  Akihiro Mutou ,  Yukitaka Wada ,  Hidehiko Kudou ,  Tateo Ono ,  Hisashi Nomura

发明人： Shinichi Inoue ,  Akihiro Mutou ,  Yukitaka Wada ,  Hidehiko Kudou ,  Tateo Ono ,  Hisashi Nomura

IPC分类号： B01J23/00 ,  C01G23/047

CPC分类号： C01G23/0532 ,  B01J21/063 ,  B01J27/19 ,  B01J35/002 ,  B01J37/0215 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C10G45/00

摘要： This invention provides layered porous titanium oxide comprising an inorganic oxide as a core and titanium oxide deposited on the surface of the inorganic oxide, wherein the titanium localization index B/A represented by the ratio of the proportion of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) determined by X-ray photoelectron spectroscopy (XPS) [B=Ti XPS/(Ti XPS+M XPS)] to the bulk mixing molar ratio of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) [A=Ti/(Ti+M)] is 1.6 or more and the titanium oxide is deposited on the surface of the inorganic oxide so as to be chemically and/or microscopically united to the inorganic oxide and also provides a process for producing the same and a catalyst comprising the same. The layered porous titanium oxide of this invention has a regulated pore structure, a large specific surface area, and excellent mechanical strength and is useful as a catalyst or a catalyst carrier.

摘要翻译： 本发明提供了以无机氧化物为芯和沉积在无机氧化物表面上的氧化钛的层状多孔氧化钛，其中钛定位指数B / A以钛（Ti）的比例与 无机氧化物的组成金属（M）和通过X射线光电子能谱（XPS）测定的钛（Ti）[B = Ti XPS /（Ti XPS + M XPS）]与钛（Ti）的体积混合摩尔比 相对于无机氧化物的组成金属（M）和钛（Ti）[A = Ti /（Ti + M）]的总和为1.6以上，氧化钛沉积在无机氧化物的表面上， 在化学和/或显微镜下与无机氧化物结合，并提供其制备方法和包含该方法的催化剂。 本发明的层状多孔氧化钛具有调节的孔结构，大的比表面积和优异的机械强度，并且可用作催化剂或催化剂载体。

公开(公告)号：US20070140952A1

公开(公告)日：2007-06-21

申请号：US10584453

申请日：2003-12-25

申请人： Shinichi Inoue ,  Akihiro Mutou ,  Yukitaka Wada ,  Hidehiko Kudou ,  Tateo Ono ,  Hisashi Nomura

发明人： Shinichi Inoue ,  Akihiro Mutou ,  Yukitaka Wada ,  Hidehiko Kudou ,  Tateo Ono ,  Hisashi Nomura

IPC分类号： C01G23/047

CPC分类号： C01G23/0532 ,  B01J21/063 ,  B01J27/19 ,  B01J35/002 ,  B01J37/0215 ,  C01G23/047 ,  C01G23/0536 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C10G45/00

摘要： This invention provides layered porous titanium oxide comprising an inorganic oxide as a core and titanium oxide deposited on the surface of the inorganic oxide, wherein the titanium localization index B/A represented by the ratio of the proportion of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) determined by X-ray photoelectron spectroscopy (XPS) [B=TiXPS/(TiXPS+MXPS)] to the bulk mixing molar ratio of titanium (Ti) to the sum of the constituent metal (M) of the inorganic oxide and titanium (Ti) [A=Ti/(Ti+M)] is 1.6 or more and the titanium oxide is deposited on the surface of the inorganic oxide so as to be chemically and/or microscopically united to the inorganic oxide and also provides a process for producing the same and a catalyst comprising the same. The layered porous titanium oxide of this invention has a regulated pore structure, a large specific surface area, and excellent mechanical strength and is useful as a catalyst or a catalyst carrier.

摘要翻译： 本发明提供了以无机氧化物为芯和沉积在无机氧化物表面上的氧化钛的层状多孔氧化钛，其中钛定位指数B / A以钛（Ti）的比例与 无机氧化物的组分金属（M）和通过X射线光电子能谱（XPS）测定的钛（Ti）[B = Ti XPS + M （Ti）与无机氧化物的组成金属（M）和钛（Ti）[A = Ti /（Ti + M））的总和的体积混合摩尔比 ]为1.6以上，并且氧化钛沉积在无机氧化物的表面上，以便化学和/或显微结合到无机氧化物上，并且还提供其制备方法和包含其的催化剂。 本发明的层状多孔氧化钛具有调节的孔结构，大的比表面积和优异的机械强度，并且可用作催化剂或催化剂载体。

公开(公告)号：US20120318717A1

公开(公告)日：2012-12-20

申请号：US13581997

申请日：2011-03-22

申请人： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

发明人： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

IPC分类号： B01J31/38 ,  C10G45/10

CPC分类号： B01J31/38 ,  B01J21/04 ,  B01J21/063 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/06 ,  C10G45/08

摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.

摘要翻译： 提供：具有加氢脱硫活性的烃油的加氢处理催化剂，其另外通过以下方式进一步提高：在含有氧化铝水合物颗粒的水溶胶的同时并连续地将含有钛的酸性化合物的水溶液和含有碱性化合物的水溶液加入到含有水合氧化铝颗粒的水溶胶中 10至100℃，pH为4.5至6.5; 洗涤所得物以除去污染的离子; 在脱水后形成洗涤后的产品，使其具有可形成的水分含量; 干燥结果; 用含有至少一种周期表6族金属化合物，至少一种周期表第8-10族金属化合物，至少一种磷化合物和至少一种类型的磷化合物的催化组分水溶液浸渍干燥产物 的糖; 并干燥所得物; 催化剂的制造方法; 以及使用该催化剂的烃油的加氢脱硫处理方法。

公开(公告)号：US09776180B2

公开(公告)日：2017-10-03

申请号：US13581997

申请日：2011-03-22

申请人： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

发明人： Shinichi Inoue ,  Yukitaka Wada ,  Akihiro Mutou ,  Takeo Ono

IPC分类号： B01J23/85 ,  B01J31/38 ,  B01J21/04 ,  B01J21/06 ,  B01J23/883 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  C10G45/08 ,  B01J37/06 ,  B01J23/88 ,  B01J27/19 ,  B01J23/882

CPC分类号： B01J31/38 ,  B01J21/04 ,  B01J21/063 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0207 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/06 ,  C10G45/08

摘要： Provided are: a hydrotreating catalyst for hydrocarbon oil having a hydrodesulfurization activity additionally improved by: simultaneously and continuously adding an aqueous solution of an acidic compound containing titanium and an aqueous solution containing an alkaline compound to a hydrosol containing an alumina hydrate particle at a temperature of 10 to 100° C. and a pH of 4.5 to 6.5; washing the resultant to remove a contaminating ion; forming the washed product after dehydration so as to have a moisture content at which it is formable; drying the resultant; impregnating the dried product with a catalytic component aqueous solution containing at least one kind of periodic table group 6 metal compound, at least one kind of periodic table group 8-10 metal compound, at least one kind of phosphorus compound, and at least one kind of saccharide; and drying the resultant; a manufacturing method for the catalyst; and a hydrodesulfurization treatment method for hydrocarbon oil using the catalyst.