Invention Grant
US08039565B2 Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers
有权
用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
- Patent Title: Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers
- Patent Title (中): 用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系
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Application No.: US12453333Application Date: 2009-05-07
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Publication No.: US08039565B2Publication Date: 2011-10-18
- Inventor: Christophe Boisson , Vincent Monteil , Roger Spitz
- Applicant: Christophe Boisson , Vincent Monteil , Roger Spitz
- Applicant Address: CH Granges-Paccot BE Senefe
- Assignee: Michelin Recherche et Technique S.A.,Total Petrochemicals Research-Feluy
- Current Assignee: Michelin Recherche et Technique S.A.,Total Petrochemicals Research-Feluy
- Current Assignee Address: CH Granges-Paccot BE Senefe
- Agency: Buchanan, Ingersoll & Rooney PC
- Priority: FR0309930 20030813
- Main IPC: C08F4/52
- IPC: C08F4/52 ; C08F236/04 ; C08F236/06 ; B01J31/22

Abstract:
A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.
Public/Granted literature
- US20090270578A1 Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers Public/Granted day:2009-10-29
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