发明授权
US08101685B2 Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
有权
热塑性弹性体聚烯烃反应器内共混物及其模塑制品
- 专利标题: Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
- 专利标题(中): 热塑性弹性体聚烯烃反应器内共混物及其模塑制品
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申请号: US12638916申请日: 2009-12-15
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公开(公告)号: US08101685B2公开(公告)日: 2012-01-24
- 发明人: Peijun Jiang , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
- 申请人: Peijun Jiang , Armenag H. Dekmezian , Kevin R. Squire , Cesar A. Garcia-Franco
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 代理商 Darryl M. Tyus
- 主分类号: C08F8/00
- IPC分类号: C08F8/00 ; C08L23/04 ; C08L23/10
摘要:
This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.84 to 0.92 g/cm3; (b) a elongation at break of 300% or more; (c) a strain hardening index M300/M100 of at least 1.2; (d) a ratio of complex viscosity at 0.01 rad/s to the viscosity at 100 rad/s is of at least 30; and (e) a shear thinning slope of the plot of log(dynamic viscosity) versus log(frequency) less than −0.2.
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