The invention provides a method of manufacturing a power storage device which enables facilitation of manufacturing of the power storage device while a plurality of terminal portions are prevented from overlapping one another when viewed from a stacking direction. The method of manufacturing the power storage device including a plurality of electrode elements stacked with electrolyte layers interposed between them, the method includes a first step of forming the electrode element which has a generally rotationally symmetric outer shape when viewed from a stacking direction and includes a terminal portion protruding in an outward direction of the power storage device in an area of the outer shape, and a second step of stacking the plurality of electrode elements formed in the first step with the electrolyte layers interposed between them at varying angles in a stacking plane such that the terminal portions do not overlap one another when viewed from the stacking direction.