发明授权
- 专利标题: Copolycondensation polymerization of fluoropolymers
- 专利标题(中): 含氟聚合物的共聚缩聚
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申请号: US12486378申请日: 2009-06-17
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公开(公告)号: US08247614B2公开(公告)日: 2012-08-21
- 发明人: Ming-Hong Hung , Bruno Ameduri , Bernard Boutevin , Aurelien Soules
- 申请人: Ming-Hong Hung , Bruno Ameduri , Bernard Boutevin , Aurelien Soules
- 申请人地址: US DE Wilmington
- 专利权人: E I du Pont de Nemours and Company,Le Centre National de la Recherche Scientifique
- 当前专利权人: E I du Pont de Nemours and Company,Le Centre National de la Recherche Scientifique
- 当前专利权人地址: US DE Wilmington
- 主分类号: C08G63/44
- IPC分类号: C08G63/44 ; C08G73/00
摘要:
Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.
公开/授权文献
- US20100324234A1 COPOLYCONDENSATION POLYMERIZATION OF FLUOROPOLYMERS 公开/授权日:2010-12-23
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