公开(公告)号：US08247614B2

公开(公告)日：2012-08-21

申请号：US12486378

申请日：2009-06-17

申请人： Ming-Hong Hung ,  Bruno Ameduri ,  Bernard Boutevin ,  Aurelien Soules

发明人： Ming-Hong Hung ,  Bruno Ameduri ,  Bernard Boutevin ,  Aurelien Soules

IPC分类号： C08G63/44 ,  C08G73/00

CPC分类号： C08G73/08 ,  C08F8/30 ,  C08F214/222 ,  C08F2800/10 ,  C08F2810/40 ,  C08F8/00

摘要： Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.

摘要翻译： 氟化共聚物是通过共聚缩聚反应制备的，该方法包括使A）一种式N 3（Y）p-（CH 2）n -R-（CH 2）m - （Y）pN 3的遥爪氟代叠氮化物，其中Y是SO，SO 2， C 6 H 4或CO，p = 0或1，n和m独立地为1至4，R选自i）C 3 -C 10氟亚烷基，ii）C 3 -C 10氟代亚烷基，iii） 取代的芳基，iv）包含偏二氟乙烯和全氟（甲基乙烯基醚）的共聚单元的低聚物，v）包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物，vi）包含四氟乙烯和全氟（甲基乙烯基醚）共聚单元的低聚物 ）和vii）包含四氟乙烯和烃烯烃的共聚单元的低聚物，B）在二卤化铜催化剂存在下的遥爪二炔或二腈化合物。

公开(公告)号：US20100324234A1

公开(公告)日：2010-12-23

申请号：US12486378

申请日：2009-06-17

申请人： MING-HONG HUNG ,  Bruno Ameduri ,  Bernard Boutevin ,  Aurelien Soules

发明人： MING-HONG HUNG ,  Bruno Ameduri ,  Bernard Boutevin ,  Aurelien Soules

IPC分类号： C08F4/10

CPC分类号： C08G73/08 ,  C08F8/30 ,  C08F214/222 ,  C08F2800/10 ,  C08F2810/40 ,  C08F8/00

摘要： Fluorinated copolymers are prepared via copolycondensation polymerization in a process comprising reacting A) a telechelic fluoroazido compound of formula N3(Y)p—(CH2)n—R—(CH2)m—(Y)pN3, wherein Y is SO, SO2, C6H4, or CO, p=0 or 1, n and m are independently 1 to 4, and R is selected from the group consisting of i) a C3-C10 fluoroalkylene group, ii) a C3-C10 fluoroalkoxylene group, iii) a substituted aryl group, iv) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), v) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, vi) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and vii) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin with B) a telechelic diyne or dinitrile compound in the presence of copper halide catalyst.

摘要翻译： 氟化共聚物是通过共聚缩聚反应制备的，该方法包括使A）一种式N 3（Y）p-（CH 2）n -R-（CH 2）m - （Y）pN 3的遥爪氟代叠氮化物，其中Y是SO，SO 2， C 6 H 4或CO，p = 0或1，n和m独立地为1至4，R选自i）C 3 -C 10氟亚烷基，ii）C 3 -C 10氟代亚烷基，iii） 取代的芳基，iv）包含偏二氟乙烯和全氟（甲基乙烯基醚）的共聚单元的低聚物，v）包含偏二氟乙烯和六氟丙烯的共聚单元的低聚物，vi）包含四氟乙烯和全氟（甲基乙烯基醚）共聚单元的低聚物 ）和vii）包含四氟乙烯和烃烯烃的共聚单元的低聚物，B）在二卤化铜催化剂存在下的遥爪二炔或二腈化合物。

公开(公告)号：US09184459B2

公开(公告)日：2015-11-10

申请号：US13823991

申请日：2011-09-21

申请人： Pierrick Buvat ,  Jannick Bigarre ,  Renaud Perrin ,  Bruno Ameduri ,  Aurelien Soules ,  Bernard Boutevin

发明人： Pierrick Buvat ,  Jannick Bigarre ,  Renaud Perrin ,  Bruno Ameduri ,  Aurelien Soules ,  Bernard Boutevin

IPC分类号： H01M8/10 ,  C08F8/36 ,  C08J3/24 ,  C08J5/22 ,  C08F8/30 ,  C08F112/08 ,  C08F112/14 ,  C08F12/08 ,  C08F12/30 ,  C08F293/00 ,  H01M8/02

CPC分类号： H01M8/1039 ,  C08F8/30 ,  C08F8/36 ,  C08F12/08 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F293/005 ,  C08F2438/00 ,  C08F2810/40 ,  C08J3/24 ,  C08J3/246 ,  C08J5/2237 ,  C08J2353/00 ,  H01M8/0289 ,  H01M8/1018 ,  H01M8/1023 ,  Y02E60/521 ,  C08F2/38

摘要： The invention relates to a polymer comprising at least one polymeric chain of a first type, the said chain comprising at least two blocks, the same or different, the said blocks comprising repeat units derived from the polymerisation of styrene monomers, the said units comprising at least one phenyl pendant group carrying at least one —SO3R group, R possibly being a hydrogen atom, an alkyl group or cationic counter-ion, the said two blocks being separated by a spacer group, the spacer group is a perfluorocarbon group.

摘要翻译： 本发明涉及包含至少一种第一类聚合物链的聚合物，所述链包含至少两个嵌段，相同或不同的所述嵌段包含衍生自苯乙烯单体聚合的重复单元，所述单元包含在 至少一个携带至少一个-SO 3 R基团的苯基侧基，R可能是氢原子，烷基或阳离子抗衡离子，所述两个嵌段被间隔基隔开，间隔基是全氟化碳基团。