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US08258354B2 Producing short chain perfluoroalkyl iodides 有权
生产短链全氟烷基碘化物

Producing short chain perfluoroalkyl iodides
Abstract:
An improved process for producing perfluoroalkyl iodides of formula (I) F(CF2CF2)n—I  (I) wherein n is an integer from 2 to 3, wherein the improvement comprises contacting at least one perfluoroalkyl iodide of formula (II) and at least one perfluoroalkyl iodide of formula (III) F(CF2CF2)m—I  (II) F(CF2CF2)p—I  (III) wherein m is an integer greater than or equal to 3, and p is an integer equal to or lower than 2, at a) a molar ratio of formula (III) to formula (II) of from about 1:1 to about 6:1, b) a residence time of from about 1 to about 9 seconds, and c) a temperature of from about 450° C. to about 495° C.
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