Invention Grant
- Patent Title: Supported metallocene catalysts
- Patent Title (中): 负载金属茂催化剂
-
Application No.: US12882268Application Date: 2010-09-15
-
Publication No.: US08299188B2Publication Date: 2012-10-30
- Inventor: William Gauthier , David Rauscher , Jun Tian , Nathan Williams
- Applicant: William Gauthier , David Rauscher , Jun Tian , Nathan Williams
- Applicant Address: US TX Houston
- Assignee: Fina Technology, Inc.
- Current Assignee: Fina Technology, Inc.
- Current Assignee Address: US TX Houston
- Main IPC: C08F4/6592
- IPC: C08F4/6592 ; C08F4/642 ; C08F210/02 ; C08F210/06 ; B01J31/22

Abstract:
Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR′2)MQn (1) or by the formula: B′(Cp′R′aR′b)(Fl′)M′Q′n′ (2) In the formulas Cp and Cp′ are substituted cyclopentadienyl groups, Fl and Fl′ are fluorenyl groups, and B and B′ are structural bridges. R′ are substituents at the 2 and 7 positions, Ra and R′a are substituents distal to the bridge, and Rb and R′b are proximal to the bridge. M and M′ are transition metals, Q′ is a halogen or a C1-C4 alkyl group; and n′ is an integer of from 0-4.
Public/Granted literature
- US20110112262A1 SUPPORTED METALLOCENE CATALYSTS Public/Granted day:2011-05-12
Information query
IPC分类: