Invention Grant
- Patent Title: Production of a water-absorbing resin to which a particulate additive is admixed
- Patent Title (中): 生产混合有微粒添加剂的吸水性树脂
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Application No.: US12861338Application Date: 2010-08-23
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Publication No.: US08349946B2Publication Date: 2013-01-08
- Inventor: Uwe Stueven , Rüdiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
- Applicant: Uwe Stueven , Rüdiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Marshall, Gerstein & Borun LLP
- Priority: DE102005062929 20051229
- Main IPC: C08G18/63
- IPC: C08G18/63

Abstract:
The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5. The resin powder is recycled fine-sized material for example. Not only the residual monomer content, specifically the residual crosslinker content, but also the level of extractables in the water-absorbing resin are reduced by the method of addition described. A high fraction of additives can be incorporated without the properties of the water-absorbing resin obtained being adversely affected. The additives enter a sufficiently firm bond with the resin, so that no excessive dusting occurs on exposure to mechanical stress.
Public/Granted literature
- US20100324212A1 Production of a Water-Absorbing Resin to Which a Particulate Additive is Admixed Public/Granted day:2010-12-23
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