发明授权
- 专利标题: Production of a water-absorbing resin to which a particulate additive is admixed
- 专利标题(中): 生产混合有微粒添加剂的吸水性树脂
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申请号: US12861338申请日: 2010-08-23
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公开(公告)号: US08349946B2公开(公告)日: 2013-01-08
- 发明人: Uwe Stueven , Rüdiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
- 申请人: Uwe Stueven , Rüdiger Funk , Matthias Weismantel , Thomas Daniel , Annemarie Hillebrecht , Dominicus van Esbroeck , Karl J. Possemiers
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Marshall, Gerstein & Borun LLP
- 优先权: DE102005062929 20051229
- 主分类号: C08G18/63
- IPC分类号: C08G18/63
摘要:
The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5. The resin powder is recycled fine-sized material for example. Not only the residual monomer content, specifically the residual crosslinker content, but also the level of extractables in the water-absorbing resin are reduced by the method of addition described. A high fraction of additives can be incorporated without the properties of the water-absorbing resin obtained being adversely affected. The additives enter a sufficiently firm bond with the resin, so that no excessive dusting occurs on exposure to mechanical stress.
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