发明授权
US08362183B2 MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins
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基于MeAPO分子筛的MTO方法与OCP方法结合制备烯烃
- 专利标题: MTO process based on MeAPO molecular sieves combined with an OCP process to make olefins
- 专利标题(中): 基于MeAPO分子筛的MTO方法与OCP方法结合制备烯烃
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申请号: US12530875申请日: 2008-03-10
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公开(公告)号: US08362183B2公开(公告)日: 2013-01-29
- 发明人: Walter Vermeiren , Nikolai Nesterenko
- 申请人: Walter Vermeiren , Nikolai Nesterenko
- 申请人地址: BE Seneffe (Feluy)
- 专利权人: Total Petrochemicals Research Feluy
- 当前专利权人: Total Petrochemicals Research Feluy
- 当前专利权人地址: BE Seneffe (Feluy)
- 优先权: EP07104063 20070313
- 国际申请: PCT/EP2008/052816 WO 20080310
- 国际公布: WO2008/110530 WO 20080918
- 主分类号: C08F210/00
- IPC分类号: C08F210/00 ; C08F110/06 ; C08F110/02 ; C07C1/00
摘要:
A process to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is disclosed. The process includes contacting the feedstock in a primary reactor with a catalyst that includes a metalloaluminophosphate (MeAPO) molecular sieve to form a first reactor effluent that includes a light olefins and a heavy hydrocarbon fraction. The process further includes separating the light olefins from the heavy hydrocarbon fraction and contacting the heavy hydrocarbon fraction in a second reactor to convert the heavy hydrocarbon fraction to light olefins. The MeAPO molecular sieve is expressed by the formula HxMeyAlzPkO2 where y+z+k=1, x is less than or equal to y, y is from 0.0008 to 0.4, z is from 0.25 to 0.67, and k is from 0.2 to 0.67. The MeAPO molecular sieve has a predominantly plate crystal morphology where the width divided by the thickness is greater than or equal to 10.
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