发明授权
- 专利标题: Deoxygenation of fatty acids for preparation of hydrocarbons
- 专利标题(中): 用于制备碳氢化合物的脂肪酸脱氧
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申请号: US13620268申请日: 2012-09-14
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公开(公告)号: US08388829B2公开(公告)日: 2013-03-05
- 发明人: Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
- 申请人: Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
- 申请人地址: US WA Richland
- 专利权人: Battelle Memorial Institute
- 当前专利权人: Battelle Memorial Institute
- 当前专利权人地址: US WA Richland
- 代理机构: Klarquist Sparkman, LLP
- 主分类号: C10M101/00
- IPC分类号: C10M101/00 ; C10M177/00 ; C10G71/00
摘要:
Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
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