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公开(公告)号：US08366907B2
公开(公告)日：2013-02-05
申请号：US12848887
申请日：2010-08-02
IPC分类号： C10M101/00 , C10M177/00 , C10G71/00
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
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公开(公告)号：US20130018213A1
公开(公告)日：2013-01-17
申请号：US13620197
申请日：2012-09-14
IPC分类号： C07C1/22
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
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公开(公告)号：US08882990B2
公开(公告)日：2014-11-11
申请号：US13620197
申请日：2012-09-14
IPC分类号： C10M101/00 , C10M177/00 , C10G71/00 , C10G3/00 , B01J23/62 , C11C3/00 , C10L1/12 , B01J37/02 , B01J21/18 , B01J21/06 , B01J23/652 , C10L1/08
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
摘要翻译： 公开了通过脱氧（脱羧/脱羰/脱水）脂肪酸制备可再生柴油以生产烃的方法的实施方案。 将脂肪酸暴露于选自a）Pt和MO3的ZrO 2上的催化剂（M为W，Mo或其组合），或b）Pt / Ge或Pt / Sn在碳上，催化剂脱羧至少10％ 的脂肪酸。 在具体实施方案中，催化剂相对于催化剂质量基本上由0.7重量％的Pt和12重量％的WO 3组成，或者催化剂基本上由a）5重量％的Pt和b）0.5重量％的Ge或0.5重量％的Sn ，相对于催化剂的质量。 在不加入氢气的情况下进行脱氧，并且小于100psi。 在脂肪酸进料中脱氧至少10％脂肪酸的催化剂的公开实施方案，并且能够使脂肪酸脱氧至少200分钟至超过350小时。
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公开(公告)号：US20130008080A1
公开(公告)日：2013-01-10
申请号：US13620268
申请日：2012-09-14
IPC分类号： C10L1/12
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
摘要翻译： 公开了通过脱氧（脱羧/脱羰/脱水）脂肪酸制备可再生柴油以生产烃的方法的实施方案。 将脂肪酸暴露于选自a）Pt和MO3的ZrO 2上的催化剂（M为W，Mo或其组合），或b）Pt / Ge或Pt / Sn在碳上，催化剂脱羧至少10％ 的脂肪酸。 在具体实施方案中，催化剂相对于催化剂质量基本上由0.7重量％的Pt和12重量％的WO 3组成，或者催化剂基本上由a）5重量％的Pt和b）0.5重量％的Ge或0.5重量％的Sn ，相对于催化剂的质量。 在不加入氢气的情况下进行脱氧，并且小于100psi。 在脂肪酸进料中脱氧至少10％脂肪酸的催化剂的公开实施方案，并且能够使脂肪酸脱氧至少200分钟至超过350小时。
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公开(公告)号：US20120029250A1
公开(公告)日：2012-02-02
申请号：US12848887
申请日：2010-08-02
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
摘要翻译： 公开了通过脱氧（脱羧/脱羰/脱水）脂肪酸制备可再生柴油以生产烃的方法的实施方案。 将脂肪酸暴露于选自a）Pt和MO3的ZrO 2上的催化剂（M为W，Mo或其组合），或b）Pt / Ge或Pt / Sn在碳上，催化剂脱羧至少10％ 的脂肪酸。 在具体实施方案中，催化剂相对于催化剂质量基本上由0.7重量％的Pt和12重量％的WO 3组成，或者催化剂基本上由a）5重量％的Pt和b）0.5重量％的Ge或0.5重量％的Sn ，相对于催化剂的质量。 在不加入氢气的情况下进行脱氧，并且小于100psi。 在脂肪酸进料中脱氧至少10％脂肪酸的催化剂的公开实施方案，并且能够使脂肪酸脱氧至少200分钟至超过350小时。
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公开(公告)号：US08388829B2
公开(公告)日：2013-03-05
申请号：US13620268
申请日：2012-09-14
IPC分类号： C10M101/00 , C10M177/00 , C10G71/00
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
摘要翻译： 公开了通过脱氧（脱羧/脱羰/脱水）脂肪酸制备可再生柴油以生产烃的方法的实施方案。 将脂肪酸暴露于选自a）Pt和MO3的ZrO 2上的催化剂（M为W，Mo或其组合），或b）Pt / Ge或Pt / Sn在碳上，催化剂脱羧至少10％ 的脂肪酸。 在具体实施方案中，催化剂相对于催化剂质量基本上由0.7重量％的Pt和12重量％的WO 3组成，或者催化剂基本上由a）5重量％的Pt和b）0.5重量％的Ge或0.5重量％的Sn ，相对于催化剂的质量。 在不加入氢气的情况下进行脱氧，并且小于100psi。 在脂肪酸进料中脱氧至少10％脂肪酸的催化剂的公开实施方案，并且能够使脂肪酸脱氧至少200分钟至超过350小时。
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7.发明申请SYSTEMS AND PROCESSES FOR CONVERSION OF ETHYLENE FEEDSTOCKS TO HYDROCARBON FUELS 有权将乙烯进料转化为烃燃料的系统和方法公开(公告)号：US20160194572A1
公开(公告)日：2016-07-07
申请号：US14528185
申请日：2014-10-30
申请人： Michael A. Lilga , Richard T. Hallen , Karl O. Albrecht , Alan R. Cooper , John G. Frye , Karthi Ramasamy
发明人： Michael A. Lilga , Richard T. Hallen , Karl O. Albrecht , Alan R. Cooper , John G. Frye , Karthi Ramasamy
CPC分类号： C10L1/04 , C07C2/12 , C07C2/24 , C07C2/66 , C07C5/03 , C07C2521/04 , C07C2521/12 , C07C2523/42 , C07C2523/755 , C07C2529/06 , C07C2529/40 , C07C2529/70 , C07C2529/76 , C10G3/00 , C10G29/205 , C10G45/00 , C10G50/00 , C10G69/123 , C10G69/126 , C10G2300/1081 , C10G2300/1092 , C10G2300/1096 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C10L2290/24 , C10L2290/543 , Y02P30/42
摘要： Systems, processes, and catalysts are disclosed for obtaining fuels and fuel blends containing selected ratios of open-chain and closed-chain fuel-range hydrocarbons suitable for production of alternate fuels including gasolines, jet fuels, and diesel fuels. Fuel-range hydrocarbons may be derived from ethylene-containing feedstocks and ethanol-containing feedstocks.
摘要翻译： 公开了用于获得燃料和燃料混合物的系统，方法和催化剂，所述燃料和燃料混合物包含适合生产包括汽油，喷气燃料和柴油燃料在内的替代燃料的开链和闭式燃料范围烃的选定比例。 燃料范围烃可以衍生自含乙烯的原料和含乙醇的原料。
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8.发明申请SYSTEMS AND PROCESSES FOR CONVERSION OF ETHYLENE FEEDSTOCKS TO HYDROCARBON FUELS 有权将乙烯进料转化为烃燃料的系统和方法公开(公告)号：US20160194257A1
公开(公告)日：2016-07-07
申请号：US14528160
申请日：2014-10-30
申请人： Michael A. Lilga , Richard T. Hallen , Karl O. Albrecht , Alan R. Cooper , John G. Frye , Karthi Ramasamy
发明人： Michael A. Lilga , Richard T. Hallen , Karl O. Albrecht , Alan R. Cooper , John G. Frye , Karthi Ramasamy
CPC分类号： C07C2/24 , B01J8/04 , B01J21/04 , B01J21/12 , B01J23/42 , B01J23/755 , B01J29/072 , B01J29/084 , B01J29/40 , B01J29/7007 , B01J29/7615 , B01J29/90 , B01J35/0006 , B01J37/0201 , B01J38/02 , B01J2208/02 , B01J2208/027 , C07C1/20 , C07C1/24 , C07C2/12 , C07C5/03 , C07C2521/12 , C07C2523/755 , C07C2529/06 , C07C2529/072 , C07C2529/14 , C07C2529/24 , C07C2529/46 , C07C2529/68 , C07C2529/70 , C07C2529/76 , C07C2529/85 , C10G3/00 , C10G45/00 , C10G50/00 , C10G69/126 , C10G2300/1092 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P20/52 , Y02P20/584 , Y02P30/42 , C07C11/04 , C07C11/02
摘要： Systems, processes, and catalysts are disclosed for obtaining fuel and fuel blends containing selected ratios of open-chain and closed-chain fuel-range hydrocarbons suitable for production of alternate fuels including gasolines, jet fuels, and diesel fuels. Fuel-range hydrocarbons may be derived from ethylene-containing feedstocks and ethanol-containing feedstocks.
摘要翻译： 公开了用于获得燃料和燃料混合物的系统，方法和催化剂，所述燃料和燃料共混物包含适合于生产包括汽油，喷气燃料和柴油燃料的替代燃料的开链和闭链燃料范围烃的选定比例。 燃料范围烃可以衍生自含乙烯的原料和含乙醇的原料。
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公开(公告)号：US20100152470A1
公开(公告)日：2010-06-17
申请号：US12712100
申请日：2010-02-24
IPC分类号： C07D307/46
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.
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10.发明授权Hydroxymethylfurfural reduction methods and methods of producing furandimethanol 有权羟甲基糠醛还原方法和生产呋喃二甲醇的方法公开(公告)号：US08367851B2
公开(公告)日：2013-02-05
申请号：US13173942
申请日：2011-06-30
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译： 提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。 将H2置于反应器中，并使原料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂在小于或等于250的温度下接触 氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H2和氢化催化剂。 在30℃或更高的温度下，HMF相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器提供包含HMF的进料。 进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。
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