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US08394897B2 Production of vinylidene-terminated polyolefins via quenching with monosulfides 有权
通过用一硫化物淬火制备亚乙烯基封端的聚烯烃

Production of vinylidene-terminated polyolefins via quenching with monosulfides
Abstract:
Provided herein are methods for a vinylidene terminated polyolefin comprising: a. ionizing a polyolefin in the presence of a Lewis acid to form an ionized polyolefin; b. reacting the ionized polyolefin from step (a) with one or more dihydrocarbylmonosulfides; and c. reacting the product of step (b) with one or more proton acceptor compounds. In some embodiments, the dihydrocarbylmonosulfide has the formula: R1—S—R2 wherein R1 and R2 are each, independently, hydrocarbyl.
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