FERROELECTRIC POLYMERS FROM DEHYDROFLUORINATED PVDF

    公开(公告)号:US20180230249A1

    公开(公告)日:2018-08-16

    申请号:US15434442

    申请日:2017-02-16

    发明人: Henry A. Sodano

    IPC分类号: C08F8/26 H01L41/45

    摘要: A β-phase PVDF is prepared through a controllable dehydrofluorination under either a basic or high temperature condition. PVDF is degraded by losing hydrogen fluoride (HF) and either carbon-carbon double bonds form in the molecular backbone or single bonds form crosslinking the two polymer chains. These changes in structure influence the crystallization behavior of PVDF and therefore, influence the electrical properties by changing the arrangement of the dipoles.

    Amine-Containing Compounds for Enhancing the Activity of ATRP Catalysts and Removal of the Terminal Halogen Groups from the ATRP Polymer Products
    8.
    发明申请
    Amine-Containing Compounds for Enhancing the Activity of ATRP Catalysts and Removal of the Terminal Halogen Groups from the ATRP Polymer Products 审中-公开
    用于提高ATRP催化剂活性和从ATRP聚合物产品中除去末端卤素基团的含胺化合物

    公开(公告)号:US20090156771A1

    公开(公告)日:2009-06-18

    申请号:US11958336

    申请日:2007-12-17

    IPC分类号: C08F8/26 C07F1/08

    摘要: Disclosed are new, highly active and versatile atom transfer radical polymerization (ATRP) catalysts. These catalysts catalyze ATRP for acrylates, methacrylates, and styrenes at surprisingly low concentrations. These catalysts mediated ATRP at a catalyst/initiator molar ratio at 0.005 and produced polymers with well-controlled molecular weights and low polydispersities. ATRP occurred even at a catalyst/initiator molar ratio as low as 0.001 with metal concentration in the produced polymers as low as 6-8 ppm. Amine-containing compounds, such as triethylamine, can significantly increase the catalyst activity of theses catalysts. The amine compounds can also used to the terminal halogen groups such as Br and Cl in the polymers prepared by ATRP.

    摘要翻译: 公开了新的,高活性和通用的原子转移自由基聚合(ATRP)催化剂。 这些催化剂以令人惊讶的低浓度催化丙烯酸酯,甲基丙烯酸酯和苯乙烯的ATRP。 这些催化剂以0.005的催化剂/引发剂摩尔比介导ATRP,并产生具有良好控制的分子量和低多分散性的聚合物。 即使催化剂/引发剂摩尔比低至0.001,生成的聚合物中的金属浓度低至6-8ppm也发生ATRP。 含胺化合物如三乙胺可显着提高这些催化剂的催化剂活性。 在ATRP制备的聚合物中,胺化合物也可用于末端卤素基团如Br和Cl。