发明授权
US08399706B2 Chiral tetraaminophosphonium salts, catalyst for asymmetric synthesis and method for producing chiral β-nitroalcohol 有权
手性四氨基鏻盐,用于不对称合成的催化剂和用于制备手性和次硝基醇的方法

Chiral tetraaminophosphonium salts, catalyst for asymmetric synthesis and method for producing chiral β-nitroalcohol
摘要:
A chiral tetraaminophosphonium salt represented by formula (1) and a method for producing chiral β-nitroalcohol comprising reacting an aldehyde or a ketone and a nitroalkane in the presence of the chiral tetraaminophosphonium salt represented by formula (1) and a base, or in the presence of a conjugated base of the chiral tetraaminophosphonium salt represented by formula (1): wherein R1 to R4 are independently a hydrogen atom or a monovalent hydrocarbon group; and, R1 and R2 are different groups or R3 and R4 are different groups.
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