发明授权
- 专利标题: Catalyst composition for oligomerization of ethylene oligomerization process and method for its preparation
- 专利标题(中): 用于低聚乙烯低聚方法的催化剂组合物及其制备方法
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申请号: US12735072申请日: 2008-11-13
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公开(公告)号: US08481444B2公开(公告)日: 2013-07-09
- 发明人: Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
- 申请人: Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi
- 申请人地址: SA Riyadh
- 专利权人: Saudi Basic Industries Corporation
- 当前专利权人: Saudi Basic Industries Corporation
- 当前专利权人地址: SA Riyadh
- 代理机构: Cantor Colburn LLP
- 优先权: EP07024098 20071212
- 国际申请: PCT/EP2008/009585 WO 20081113
- 国际公布: WO2009/074203 WO 20090618
- 主分类号: B01J31/04
- IPC分类号: B01J31/04 ; C07C2/22
摘要:
Catalyst composition for the oligomerization of ethylene, comprising (i) an at least partially hydrolyzed transition metal compound, obtainable by controlled addition of water to a transition metal compound having the general formula MXm(OR′)4-m or MXm(OOCR′)4-m, wherein R′ is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is halogen, preferably Cl or Br, and m is from 0 to 4; preferably 0-3; and (ii) an organoaluminum compound as a cocatalyst, wherein the molar ratio of water and transition metal compound is within a range of between about (0.01-3):1; a process for oligomerization of ethylene and a method for preparing the catalyst composition.
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