A method and apparatus for removing carbon dioxide from a synthesis gas stream containing hydrogen is disclosed. The method includes absorbing the carbon dioxide using a physical solvent under high pressure and then liberating the carbon dioxide in a series of expansion stages where the pressure on the solvent is reduced. The expansion ratio increases with each expansion stage. The apparatus includes expansion stages having throttling devices and expansion tanks operated at increasing expansion ratios. Carbon dioxide is liberated in this manner so as to minimize the energy required compress for transport via a pipe line for sequestration of the gas. Sequestration of the carbon dioxide is preferred to atmospheric venting to curb the release of greenhouse gases.