发明授权
- 专利标题: Process for producing synthetic liquid hydrocarbons and reactor for Fischer-Tropsch synthesis
- 专利标题(中): 合成液烃的制备方法和费 - 托合成反应器
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申请号: US13574710申请日: 2011-01-31
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公开(公告)号: US08524787B2公开(公告)日: 2013-09-03
- 发明人: Vadim Sergeevich Ermolaev , Vladimir Zalmanovich Mordkovich , Igor Grigorievich Solomonik , Igor Vladimirovich Derevich , Lilia Vadimovna Sineva , Eduard Borisovich Mitberg
- 申请人: Vadim Sergeevich Ermolaev , Vladimir Zalmanovich Mordkovich , Igor Grigorievich Solomonik , Igor Vladimirovich Derevich , Lilia Vadimovna Sineva , Eduard Borisovich Mitberg
- 申请人地址: VG Road Town, Tortola
- 专利权人: Infra Technologies Ltd.
- 当前专利权人: Infra Technologies Ltd.
- 当前专利权人地址: VG Road Town, Tortola
- 代理机构: Knobbe, Martens, Olson & Bear, LLP
- 优先权: RU2010103081 20100201
- 国际申请: PCT/RU2011/000054 WO 20110131
- 国际公布: WO2011/093749 WO 20110804
- 主分类号: C07C27/00
- IPC分类号: C07C27/00 ; F28D7/00
摘要:
The disclosure relates to petrochemistry, gas chemistry, coal chemistry, particularly to a synthesis of hydrocarbons C5 and higher from CO and H2 under the Fischer-Tropsch reaction; the invention relates to a process and a system for producing synthetic liquid hydrocarbons. A process for producing synthetic liquid hydrocarbons is provided by catalytic converting syngas under the Fischer-Tropsch reaction on a fixed catalyst bed in a vertical shell and tube reactor with coolant supply into shell wherein as soon as the syngas conversion degree achieves 60-80%, a pressure gradient along the tubes is reduced below 0.1 bar/m and this value is maintained during the whole process. A reactor for Fischer-Tropsch synthesis is provided comprising tubes with catalyst in a shell, the ratio of the tube diameter at the tube outlet to the diameter at the inlet is from 1.5/1 to 2.5/1. The invention gives a possibility to achieve the optimum temperature range in the catalyst bed; it improves heat and mass-transfer and shut out an accumulation of the liquid products in the bottom of the tubes.
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