公开(公告)号：US08524787B2

公开(公告)日：2013-09-03

申请号：US13574710

申请日：2011-01-31

申请人： Vadim Sergeevich Ermolaev ,  Vladimir Zalmanovich Mordkovich ,  Igor Grigorievich Solomonik ,  Igor Vladimirovich Derevich ,  Lilia Vadimovna Sineva ,  Eduard Borisovich Mitberg

发明人： Vadim Sergeevich Ermolaev ,  Vladimir Zalmanovich Mordkovich ,  Igor Grigorievich Solomonik ,  Igor Vladimirovich Derevich ,  Lilia Vadimovna Sineva ,  Eduard Borisovich Mitberg

IPC分类号： C07C27/00 ,  F28D7/00

CPC分类号： B01J8/067 ,  B01J2208/00238 ,  B01J2219/1946 ,  C10G2/332 ,  C10G2/341 ,  C10G2300/1022 ,  C10G2300/4012

摘要： The disclosure relates to petrochemistry, gas chemistry, coal chemistry, particularly to a synthesis of hydrocarbons C5 and higher from CO and H2 under the Fischer-Tropsch reaction; the invention relates to a process and a system for producing synthetic liquid hydrocarbons. A process for producing synthetic liquid hydrocarbons is provided by catalytic converting syngas under the Fischer-Tropsch reaction on a fixed catalyst bed in a vertical shell and tube reactor with coolant supply into shell wherein as soon as the syngas conversion degree achieves 60-80%, a pressure gradient along the tubes is reduced below 0.1 bar/m and this value is maintained during the whole process. A reactor for Fischer-Tropsch synthesis is provided comprising tubes with catalyst in a shell, the ratio of the tube diameter at the tube outlet to the diameter at the inlet is from 1.5/1 to 2.5/1. The invention gives a possibility to achieve the optimum temperature range in the catalyst bed; it improves heat and mass-transfer and shut out an accumulation of the liquid products in the bottom of the tubes.

摘要翻译： 本公开涉及石油化学，气体化学，煤化学，特别是在费 - 托反应下合成来自CO和H 2的烃C5和更高的烃; 本发明涉及一种用于生产合成液体烃的方法和系统。 制备合成液体烃的方法是通过在固体催化剂床上的费 - 托反应中将合成气催化转化为垂直壳管式反应器，其中冷却剂供应到壳中，其中一旦合成气转化度达到60-80％ 沿着管的压力梯度降低到0.1巴/ m以下，并且在整个过程中保持该值。 提供了用于费 - 托合成的反应器，其包括在壳中具有催化剂的管，管出口处的管直径与入口直径之比为1.5 / 1-2.5 / 1。 本发明提供了在催化剂床中达到最佳温度范围的可能性; 它改善了热量和质量传递，并阻止了液体产品在管底部的积聚。

公开(公告)号：US20170073226A1

公开(公告)日：2017-03-16

申请号：US15125197

申请日：2015-03-19

申请人： Vladimir Z. MORDKOVICH ,  Igor Vladimirovich DEREVICH ,  Vadim Sergeevich ERMOLAEV ,  Ilia Sergeevich ERMOLAEV ,  Eduard Borisovich MITBERG ,  Igor Grigorievich SOLOMONIK ,  Petr Ivanovich KULCHAKOVSKY ,  Infra Carbon Limited

发明人： Vladimir Z. Mordkovich ,  Igor V. Derevich ,  Vadim S. Ermolaev ,  Ilia S. Ermolaev ,  Eduard B. Mitberg ,  Igor G. Solomonik ,  Petr I. Kulchakovsky

IPC分类号： C01B3/36 ,  B01J19/02 ,  B01J7/00

CPC分类号： C01B3/36 ,  B01J7/00 ,  B01J8/0292 ,  B01J8/06 ,  B01J12/005 ,  B01J19/02 ,  B01J2208/00185 ,  B01J2208/00362 ,  B01J2208/00513 ,  B01J2208/00548 ,  B01J2208/00628 ,  B01J2219/02 ,  C01B2203/0255 ,  C01B2203/0872 ,  C01B2203/0883 ,  C01B2203/1241 ,  C01B2203/1282

摘要： The invention is for use in gas chemistry for producing hydrogen-containing gas on the base of a CO and H2 mixture (syngas) from natural gas and other hydrocarbon gases. The object of the invention is to suppress side reactions resulting in soot formation when conducting the process in high productivity mode, and also to provide for an uncomplicated reactor design while maintaining compact dimensions thereof. The method for producing a hydrogen-containing gas comprises mixing natural gas with oxygen, partially oxidizing the natural gas with oxygen at a temperature ranging from 1300° C. to 1700° C. resulting in obtaining hydrogen-containing gas, and cooling the stream of the hydrogen-containing gas produced. Said cooling is performed until the temperature drops below 550° C. and at a rate above 100000° C./sec. The reactor comprises the following steps, which are arranged in series along the technological process: means for supplying natural gas and oxygen, a natural gas and oxygen mixing zone, a zone for conducting the reaction by partially oxidizing the natural gas with oxygen, and a zone for cooling the stream of the hydrogen-containing gas produced, which is equipped with a cooling body of revolution in order to provide an intensive cooling of the stream of hydrogen-containing gas by contacting thereof with said body of revolution.

摘要翻译： 本发明用于在天然气和其它烃气体的CO和H 2混合物（合成气）基础上生产含氢气体的气体化学。 本发明的目的是抑制在高生产率模式下进行该方法时产生烟灰形成的副反应，并且还提供了一种简单的反应器设计，同时保持其紧凑的尺寸。 含氢气体的制造方法包括将天然气与氧气混合，在1300〜1700℃的温度范围内用氧部分氧化天然气，得到含氢气体， 产生含氢气体。 进行所述的冷却，直至温度降到550℃以上，速率高于100000℃/秒。 该反应器包括以下步骤：沿着工艺流程串联布置：用于供应天然气和氧气的装置，天然气和氧气混合区，用氧气部分氧化天然气进行反应的区域，以及 用于冷却产生的含氢气体的流的区域，其配备有旋转冷却体，以通过与所述旋转体接触来提供含氢气体流的强烈冷却。

公开(公告)号：US20120322898A1

公开(公告)日：2012-12-20

申请号：US13574710

申请日：2011-01-31

申请人： Vadim Sergeevich Ermolaev ,  Vladimir Zalmanovich Mordkovic ,  Igor Grigorievich Solomonik ,  Igor Vladimirovich Derevich ,  Lilia Vadimovna Sineva ,  Eduard Borisovich Mitberg

发明人： Vadim Sergeevich Ermolaev ,  Vladimir Zalmanovich Mordkovic ,  Igor Grigorievich Solomonik ,  Igor Vladimirovich Derevich ,  Lilia Vadimovna Sineva ,  Eduard Borisovich Mitberg

IPC分类号： C07C27/00 ,  B01J19/00

CPC分类号： B01J8/067 ,  B01J2208/00238 ,  B01J2219/1946 ,  C10G2/332 ,  C10G2/341 ,  C10G2300/1022 ,  C10G2300/4012

摘要： The disclosure relates to petrochemistry, gas chemistry, coal chemistry, particularly to a synthesis of hydrocarbons C5 and higher from CO and H2 under the Fischer-Tropsch reaction; the invention relates to a process and a system for producing synthetic liquid hydrocarbons. A process for producing synthetic liquid hydrocarbons is provided by catalytic converting syngas under the Fischer-Tropsch reaction on a fixed catalyst bed in a vertical shell and tube reactor with coolant supply into shell wherein as soon as the syngas conversion degree achieves 60-80%, a pressure gradient along the tubes is reduced below 0.1 bar/m and this value is maintained during the whole process. A reactor for Fischer-Tropsch synthesis is provided comprising tubes with catalyst in a shell, the ratio of the tube diameter at the tube outlet to the diameter at the inlet is from 1.5/1 to 2.5/1. The invention gives a possibility to achieve the optimum temperature range in the catalyst bed; it improves heat and mass-transfer and shut out an accumulation of the liquid products in the bottom of the tubes.

摘要翻译： 本公开涉及石油化学，气体化学，煤化学，特别是在费 - 托反应下合成来自CO和H 2的烃C5和更高的烃; 本发明涉及一种用于生产合成液体烃的方法和系统。 制备合成液体烃的方法是通过在固定催化剂床上的费 - 托反应中将合成气催化转化成垂直管壳反应器，其中冷却剂供应到壳中，其中一旦合成气转化度达到60-80％ 沿着管的压力梯度降低到0.1巴/ m以下，并且在整个过程中保持该值。 提供了用于费 - 托合成的反应器，其包括在壳中具有催化剂的管，管出口处的管直径与入口直径之比为1.5 / 1-2.5 / 1。 本发明提供了在催化剂床中达到最佳温度范围的可能性; 它改善了热量和质量传递，并阻止了液体产品在管底部的积聚。