A fuel tank valve structure controlling emission gas in a hybrid vehicle may include a housing having one side connected with a fuel tank and the other side connected to a canister, a check valve mounted to the housing and opening or closing a first fluid passage connected between the canister and the fuel tank, a solenoid valve apparatus selectively connected with the check valve to open or close the first fluid passage to adjust an internal pressure of the fuel tank, a fuel limit vent valve apparatus mounted to the housing and selectively fluid-connecting to a space formed between the check valve and the fuel limit vent valve apparatus in the housing, and a relief valve mounted to the housing and selectively fluid-connecting the fuel tank with the canister through a second fluid passage.