发明授权
US08598280B2 Poly(meth)acrylimide having improved optical and color properties, particularly under thermal load
有权
具有改善的光学和颜色特性的聚(甲基)丙烯酰亚胺,特别是在热负载下
- 专利标题: Poly(meth)acrylimide having improved optical and color properties, particularly under thermal load
- 专利标题(中): 具有改善的光学和颜色特性的聚(甲基)丙烯酰亚胺,特别是在热负载下
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申请号: US12922627申请日: 2009-02-27
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公开(公告)号: US08598280B2公开(公告)日: 2013-12-03
- 发明人: Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
- 申请人: Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
- 申请人地址: DE Darmstadt
- 专利权人: Evonik Roehm GmbH
- 当前专利权人: Evonik Roehm GmbH
- 当前专利权人地址: DE Darmstadt
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: DE102008001695 20080509
- 国际申请: PCT/EP2009/052380 WO 20090227
- 国际公布: WO2009/135703 WO 20091112
- 主分类号: C08F8/32
- IPC分类号: C08F8/32 ; C08F8/30 ; C08F8/40
摘要:
Process for preparing molding materials MM with improved optical and color properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for color stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups. Shaped bodies obtainable by the process, especially light waveguides, have a low tendency to yellowing under thermal stress, coupled with a low haze, and also a stable and high transparency.
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