Invention Grant
- Patent Title: Cyclohexanone production process with modified post-distillation
- Patent Title (中): 环己酮生产工艺采用改性后蒸馏
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Application No.: US12809257Application Date: 2008-12-16
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Publication No.: US08618334B2Publication Date: 2013-12-31
- Inventor: Marleen Horsels , Rudy Francols Marla Jozef Parton , Johan Thomas Tinge
- Applicant: Marleen Horsels , Rudy Francols Marla Jozef Parton , Johan Thomas Tinge
- Applicant Address: NL Heerlen
- Assignee: DSM IP Assets B.V.
- Current Assignee: DSM IP Assets B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP07024764 20071220
- International Application: PCT/EP2008/067635 WO 20081216
- International Announcement: WO2009/080621 WO 20090702
- Main IPC: C08G8/10
- IPC: C08G8/10 ; B01D3/10 ; B01D3/32 ; B01J19/32

Abstract:
Methods for continuously preparing cyclohexanone from phenol make use of a catalyst having at least one catalytically active metal selected from platinum and palladium. The process includes enriching phenol in a distillation fraction as compared to a subsequent fraction, wherein the subsequent fraction includes phenol and side-products having a higher boiling point than phenol. Distillation is carried out in a vacuum distillation column equipped with trays in the lower part of the column. In an upper part of the column, i.e., in the part above the feed inlet, packing material is present instead of trays in at least part thereof. The packing material has a comparable or improved separating efficiency, and provides a reduction of the pressure drop by at least 30%, preferably more than 50%, as compared to the case with trays in the upper part, under otherwise similar distillation conditions.
Public/Granted literature
- US20110054142A1 CYCLOHEXANONE PRODUCTION PROCESS WITH MODIFIED POST-DISTILLATION Public/Granted day:2011-03-03
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