Invention Grant
US08648221B2 Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane
有权
共同生产反式-1-氯-3,3,3-三氟丙烯,反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
- Patent Title: Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane
- Patent Title (中): 共同生产反式-1-氯-3,3,3-三氟丙烯,反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
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Application No.: US13315341Application Date: 2011-12-09
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Publication No.: US08648221B2Publication Date: 2014-02-11
- Inventor: Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- Applicant: Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- Applicant Address: US NJ Morristown
- Assignee: Honeywell International Inc.
- Current Assignee: Honeywell International Inc.
- Current Assignee Address: US NJ Morristown
- Agent Bruce O. Bradford
- Main IPC: C07C17/23
- IPC: C07C17/23

Abstract:
Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro-propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3-pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HCl); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3c) the 244fa stream can be further fluorinated to form 245fa.
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