发明授权
US08648221B2 Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane
有权
共同生产反式-1-氯-3,3,3-三氟丙烯，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
- 专利标题： Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane
- 专利标题（中）： 共同生产反式-1-氯-3,3,3-三氟丙烯，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷的综合方法
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申请号： US13315341申请日： 2011-12-09
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公开(公告)号： US08648221B2公开(公告)日： 2014-02-11
- 发明人: Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- 申请人： Daniel C. Merkel , Haiyou Wang , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- 申请人地址： US NJ Morristown
- 专利权人： Honeywell International Inc.
- 当前专利权人： Honeywell International Inc.
- 当前专利权人地址： US NJ Morristown
- 代理商 Bruce O. Bradford
- 主分类号： C07C17/23
- IPC分类号： C07C17/23
摘要：
Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro-propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3-pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HCl); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3c) the 244fa stream can be further fluorinated to form 245fa.
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