发明授权
- 专利标题: Method for crystallizing (meth)acrylic acid and method for regulating content of polymerization inhibitor in product (meth)acrylic acid
- 专利标题(中): (甲基)丙烯酸结晶方法及其制备(甲基)丙烯酸中阻聚剂含量的方法
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申请号: US13322633申请日: 2010-05-27
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公开(公告)号: US08704000B2公开(公告)日: 2014-04-22
- 发明人: Kazuhiko Sakamoto , Koji Ueno , Yoshitake Ishii , Harunori Hirao , Satoshi Nakagawa
- 申请人: Kazuhiko Sakamoto , Koji Ueno , Yoshitake Ishii , Harunori Hirao , Satoshi Nakagawa
- 申请人地址: JP Osaka
- 专利权人: Nippon Shokubai Co., Ltd.
- 当前专利权人: Nippon Shokubai Co., Ltd.
- 当前专利权人地址: JP Osaka
- 代理机构: Porzio, Bromberg & Newman, P.C.
- 优先权: JP2009-132000 20090601
- 国际申请: PCT/JP2010/058997 WO 20100527
- 国际公布: WO2010/140530 WO 20101209
- 主分类号: C07C51/43
- IPC分类号: C07C51/43 ; C07C51/50
摘要:
PROBLEMThere is provided a melting method of (meth)acrylic acid crystal which is capable of providing a higher quality of (meth)acrylic acid without carrying out an additional purification treatment to (meth)acrylic acid obtained by a crystallization operation accompanied by melting of (meth)acrylic acid. In addition, there is provided a simple method for adjusting a content of polymerization inhibitor in a product (meth)acrylic acid.SOLUTIONIn the crystallization method melting (meth)acrylic acid crystal while wetting with the crystalline molten liquid, a polymerization inhibitor is added to a molten liquid melted after initiation of melting, and all of crystal is melted while circulating and feeding the molten liquid containing said polymerization inhibitor to the crystal. In addition, a content of polymerization inhibitor in product (meth)acrylic acid is adjusted by adding a predetermined amount of polymerization inhibitor corresponding to a product specification to the molten liquid melted after initiation of melting.
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