Invention Grant
US08859704B2 High pressure low density polyethylene resins with improved optical properties produced through use of highly active chain transfer agents
有权
通过使用高活性链转移剂生产出具有改善的光学性能的高压低密度聚乙烯树脂
- Patent Title: High pressure low density polyethylene resins with improved optical properties produced through use of highly active chain transfer agents
- Patent Title (中): 通过使用高活性链转移剂生产出具有改善的光学性能的高压低密度聚乙烯树脂
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Application No.: US13858640Application Date: 2013-04-08
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Publication No.: US08859704B2Publication Date: 2014-10-14
- Inventor: Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Main IPC: C08F10/02
- IPC: C08F10/02 ; C08F110/02 ; C08F2/38 ; B01J19/24

Abstract:
Disclosed is an ethylene-based polymer with a density from about 0.90 to about 0.94 in grams per cubic centimeter, with a molecular weight distribution (Mw/Mn) from about 2 to about 30, a melt index (I2) from about 0.1 to about 50 grams per 10 minutes, and further comprising sulfur from about 5 to about 4000 parts per million. The amount of sulfur is also determined based upon the total weight of the ethylene-based polymer. Also disclosed is process for making an ethylene-based polymer which includes the steps of splitting a process fluid for delivery into a tubular reactor; feeding an upstream process feed stream into a first reaction zone and at least one downstream process feed stream into at least one other reaction zone, where the process fluid has an average velocity of at least 10 meters per second; and initiating a free-radical polymerization reaction.
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