Invention Grant
- Patent Title: Process for making polyethylene terephthalate
- Patent Title (中): 制造聚对苯二甲酸乙二醇酯的方法
-
Application No.: US13256437Application Date: 2010-03-10
-
Publication No.: US08859713B2Publication Date: 2014-10-14
- Inventor: Mummaneni Venkateswara Rao , Munif Al-Munif , Zahir Bashir
- Applicant: Mummaneni Venkateswara Rao , Munif Al-Munif , Zahir Bashir
- Applicant Address: SA Riyadh
- Assignee: Saudi Basic Industries Corporation
- Current Assignee: Saudi Basic Industries Corporation
- Current Assignee Address: SA Riyadh
- Agency: Cantor Colburn LLP
- Priority: EP09075114 20090313
- International Application: PCT/EP2010/001480 WO 20100310
- International Announcement: WO2010/102795 WO 20100916
- Main IPC: C08G63/00
- IPC: C08G63/00 ; C08G63/82 ; C08G63/02 ; C08G63/86 ; C08G63/83

Abstract:
The invention relates to a process for making polyethylene terephthalate (PET) from ethylene glycol (EG), purified terephthalic acid (PTA) and optionally up to 30 mol % comonomer, using a catalyst system essentially consisting of antimony—(Sb), zinc—(Zn) and phosphorous—(P) compounds, comprising the steps of a) esterifying EG and PTA to form diethyleneglycol terephthalate and oligomers (DGT), and b) melt-phase polycondensing DGT to form polyester and EG1 wherein the Sb- and P-compounds are added in step a) and the Zn-compound is added after step a). With this process PET can be obtained that shows favorable color and optical clarity, also if recycling of EG is applied in the process, and a relatively low rate of acetaldehyde regeneration during melt-processing.
Public/Granted literature
- US20120071625A1 PROCESS FOR MAKING POLYETHYLENE TEREPHTHALATE Public/Granted day:2012-03-22
Information query