Invention Grant
- Patent Title: Process for making polyethylene terephthalate
- Patent Title (中): 制造聚对苯二甲酸乙二醇酯的方法
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Application No.: US13391432Application Date: 2010-08-17
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Publication No.: US08901271B2Publication Date: 2014-12-02
- Inventor: Munif Al-Munif , Mummaneni Venkateswara Rao , Zahir Bashir , Suresh Padmanabhan
- Applicant: Munif Al-Munif , Mummaneni Venkateswara Rao , Zahir Bashir , Suresh Padmanabhan
- Applicant Address: SA Riyadh
- Assignee: Saudi Basic Industries Corporation
- Current Assignee: Saudi Basic Industries Corporation
- Current Assignee Address: SA Riyadh
- Agency: Cantor Colburn LLP
- Priority: EP09075379 20090820
- International Application: PCT/EP2010/005115 WO 20100817
- International Announcement: WO2011/020619 WO 20110224
- Main IPC: C08G63/00
- IPC: C08G63/00 ; C08G63/85

Abstract:
The invention relates to a process for making polyethylene terephthalate (PET) from ethylene glycol (EG), purified terephthalic acid (PTA) and optionally up to 6 mol % comonomer, using a mixed metal catalyst system and comprising the steps of a) esterifying EG and PTA to form diethyleneglycol terephthalate and oligomers (DGT), and b) melt-phase polycondensing DGT to form PET and EG, wherein the catalyst system substantially consists of 70-160 ppm of Sb-compound, 20-70 ppm of Zn-compound, and 0.5-20 ppm of Ti-glycolate as active components (ppm metal based on PET). With this process that applies reduced amount of metal catalyst components PET can be obtained with high productivity, which polyester shows favorable color and optical clarity, also if recycling of EG is applied within the process.
Public/Granted literature
- US20120161358A1 PROCESS FOR MAKING POLYETHYLENE TEREPHTHALATE Public/Granted day:2012-06-28
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