Invention Grant
- Patent Title: Powerfeed polymers having improved block resistance performance
- Patent Title (中): 具有改善阻块性能的加电聚合物
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Application No.: US13889590Application Date: 2013-05-08
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Publication No.: US08907005B2Publication Date: 2014-12-09
- Inventor: Gary W. Dombrowski , Arnold S. Brownell , Aurelia de la Cuesta Sheppard , Thomas R. Tepe
- Applicant: Rohm and Haas Company
- Applicant Address: US PA Philadelphia
- Assignee: Rohm and Haas Company
- Current Assignee: Rohm and Haas Company
- Current Assignee Address: US PA Philadelphia
- Agent Andrew E. C. Merriam
- Main IPC: C08L33/06
- IPC: C08L33/06 ; C08K5/07 ; C09D113/02 ; C08F220/18 ; C09D133/10

Abstract:
The present invention provides emulsion copolymers and coating compositions containing the same having improved room temperature and hot block resistance in coatings wherein the copolymers have a broad measured glass transition temperature and are the copolymerization product of a vinyl monomer composition A and a softer vinyl monomer composition B having a Hansch parameter of at least 3.2, and containing one or more vinyl monomer M, such that each of which vinyl monomer(s) M would when homopolymerized provide a homopolymer having a measured Tg of 20° C. or less, such as, for example, 2-ethylhexyl acrylate. In addition, the present invention provides methods for making the emulsion copolymers by a powerfeed process comprising feeding vinyl monomer composition A into a reactor from a feed vessel while feeding, simultaneously or after a delay, vinyl monomer composition B into the feed vessel while polymerizing the monomers in the reactor.
Public/Granted literature
- US20130303674A1 POWERFEED POLYMERS HAVING IMPROVED BLOCK RESISTANCE PERFORMANCE Public/Granted day:2013-11-14
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