Invention Grant
- Patent Title: Preparation method of 4-aminomethylbenzoic acid
- Patent Title (中): 4-氨基甲基苯甲酸的制备方法
-
Application No.: US13522465Application Date: 2010-12-09
-
Publication No.: US08907127B2Publication Date: 2014-12-09
- Inventor: Woo Sun Kim
- Applicant: Woo Sun Kim
- Applicant Address: KR Daejeon KR Ulsan
- Assignee: NAF Co Ltd,SK Petrochemical Co Ltd
- Current Assignee: NAF Co Ltd,SK Petrochemical Co Ltd
- Current Assignee Address: KR Daejeon KR Ulsan
- Priority: KR10-2010-0003577 20100114
- International Application: PCT/KR2010/008774 WO 20101209
- International Announcement: WO2011/087211 WO 20110721
- Main IPC: C07C227/04
- IPC: C07C227/04 ; C07C249/08 ; B01J21/18 ; B01J23/40 ; B01J23/44 ; B01J23/75

Abstract:
The present invention relates to a preparation method of 4-aminomethylbenzoic acid comprising the following steps: preparing 4-carboxylbenzaldehyde or an alkyl ester thereof (methyl 4-formyl benzoate); reacting the 4-carboxylbenzaldehyde or an alkyl ester thereof (methyl 4-formyl benzoate) with hydroxyamine to oximate the same; and contact reducing 4-carboxylbenzaldehyde oxime or an alkyl ester oxime thereof obtained by the oximation, through hydrogen in a sodium hydroxide aqueous solution. Since methyl 4-hydroxyiminomethylbenzoate is reacted as a raw material in the presence of an alkali, hydrogen of a relatively low pressure can be used and a purification process is also simple, thereby enabling preparation of 4-aminomethylbenzoic acid with a low cost and high yield.
Public/Granted literature
- US20120296114A1 PREPARATION METHOD OF 4-AMINOMETHYLBENZOIC ACID Public/Granted day:2012-11-22
Information query