A structure for absorbing frontal collision energy of a vehicle absorbs frontal collision energy of a vehicle using both front side members configured to support a bumper beam disposed at a front side of a vehicle body, a shock absorber housing panel disposed outside the front side member, and a fender apron member disposed outside the shock absorber housing panel, and the structure includes: an enlarged member installed to be inclined between an outer surface of the front side member and a rear surface of the fender apron member so as to be spaced forward and apart from the outer surface of the front side member; and an enlarged frame engaged between a lower side of the fender apron member and a front mounting portion of a sub-frame.