发明授权
- 专利标题: Process for producing solvent-soluble reactive polysiloxanes
- 专利标题(中): 制备溶剂可溶性活性聚硅氧烷的方法
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申请号: US13996828申请日: 2011-12-14
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公开(公告)号: US08952117B2公开(公告)日: 2015-02-10
- 发明人: Akinori Kitamura , Naomasa Furuta , Hiroshi Suzuki
- 申请人: Akinori Kitamura , Naomasa Furuta , Hiroshi Suzuki
- 申请人地址: JP Tokyo
- 专利权人: Toagosei Co., Ltd.
- 当前专利权人: Toagosei Co., Ltd.
- 当前专利权人地址: JP Tokyo
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: JP2010-292006 20101228
- 国际申请: PCT/JP2011/078907 WO 20111214
- 国际公布: WO2012/090707 WO 20120705
- 主分类号: C08G77/06
- IPC分类号: C08G77/06 ; C08G77/20 ; C08K5/103
摘要:
The present invention is a method for producing solvent-soluble polysiloxanes which includes a condensation process of subjecting a raw material having siloxane-bond-forming groups to hydrolytic copolycondensation in the presence of a catalyst to synthesize a reactive polysiloxane represented by general formula (1), the raw material containing both an organosilicon compound (S1) having a (meth)acryloyl group and siloxane-bond-forming groups and at least one silicon compound (S2) selected from among tetraalkoxysilanes and tetrahalogenosilanes, wherein in the condensation process, the organosilicon compound (S1) and silicon compound (S2) are used at a (S2)/(S1) molar ratio of 1.8 or less, and the condensation process is conducted by adding gradually a mixture of the silicon compound (S2) and the catalyst to a raw material liquid containing the organosilicon compound (S1) and water, while keeping the molar ratio of the amount of the silicon compound (S2) to the amount of the organosilicon compound (S1) within the range of 0.001/min to 0.3/min.
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