发明授权
- 专利标题: Self limiting catalyst composition for ethylene polymerization
- 专利标题(中): 用于乙烯聚合的自限制催化剂组合物
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申请号: US13700503申请日: 2011-06-29
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公开(公告)号: US08993692B2公开(公告)日: 2015-03-31
- 发明人: Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, Jr. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
- 申请人: Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, Jr. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
- 申请人地址: US MI Midland
- 专利权人: Dow Global Technologies LLC
- 当前专利权人: Dow Global Technologies LLC
- 当前专利权人地址: US MI Midland
- 国际申请: PCT/US2011/042378 WO 20110629
- 国际公布: WO2012/003219 WO 20120105
- 主分类号: C08F4/649
- IPC分类号: C08F4/649 ; C08F2/34 ; C08F10/02 ; C08F110/02 ; C08F210/16
摘要:
A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
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