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1.发明申请PROCESS FOR TELOMERIZATION OF BUTADIENE USING A MONO-ORTHOALKOXY SUBSTITUTED CATALYST 有权使用单羟基烷氧基取代的催化剂对丁二烯进行酯化的方法公开(公告)号：US20130261342A1
公开(公告)日：2013-10-03
申请号：US13883688
申请日：2011-12-14
Applicant: John R. Briggs , Jasson T. Patton , Daryoosh Beigzadeh , Peter M. Margl , Henk Hagen , Sonet Vermaire-Louw
Inventor： John R. Briggs , Jasson T. Patton , Daryoosh Beigzadeh , Peter M. Margl , Henk Hagen , Sonet Vermaire-Louw
IPC: C07C41/06
CPC classification number: C07C41/06 , C07C1/20 , C07C41/20 , C07F9/5022 , C07C43/15 , C07C43/04 , C07C11/02
Abstract: A process for the telomerization of butadiene comprises reacting 1,3-butadiene and an alkanol, in the presence of a catalyst promoter and an alkoxydimerization catalyst comprising a Group VIII transition metal and a triarylphosphine ligand, which includes one phenyl that is mono-ortho-alkoxy substituted and at least one other phenyl including at least one substituent that withdraws electrons from the phosphorus atom. The product includes an alkoxy-substituted octadiene, which may then be used to produce 1-octene. The catalyst shows improved stability, activity and selectivity toward the alkoxy-substituted octadiene.
Abstract translation: 用于丁二烯调聚的方法包括在催化剂促进剂和包含第VIII族过渡金属和三芳基膦配体的烷氧基二聚催化剂的存在下，使1,3-丁二烯和链烷醇反应，其包括一个苯基， 烷氧基取代的和至少一种其它苯基，包括至少一个从磷原子撤出电子的取代基。 该产物包括烷氧基取代的辛二烯，然后可以用它来生产1-辛烯。 该催化剂显示改进的对烷氧基取代的辛二烯的稳定性，活性和选择性。
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2.发明授权Process for telomerization of butadiene using a mono-orthoalkoxy substituted catalyst 有权使用单 - 邻烷氧基取代催化剂调节丁二烯的方法公开(公告)号：US09174905B2
公开(公告)日：2015-11-03
申请号：US13883688
申请日：2011-12-14
Applicant: John R. Briggs , Jasson T. Patton , Daryoosh Beigzadeh , Peter M. Margl , Henk Hagen , Sonet Vermaire-Louw
Inventor： John R. Briggs , Jasson T. Patton , Daryoosh Beigzadeh , Peter M. Margl , Henk Hagen , Sonet Vermaire-Louw
CPC classification number: C07C41/06 , C07C1/20 , C07C41/20 , C07F9/5022 , C07C43/15 , C07C43/04 , C07C11/02
Abstract: A process for the telomerization of butadiene comprises reacting 1,3-butadiene and an alkanol, in the presence of a catalyst promoter and an alkoxydimerization catalyst comprising a Group VIII transition metal and a triarylphosphine ligand, which includes one phenyl that is mono-ortho-alkoxy substituted and at least one other phenyl including at least one substituent that withdraws electrons from the phosphorus atom. The product includes an alkoxy-substituted octadiene, which may then be used to produce 1-octene. The catalyst shows improved stability, activity and selectivity toward the alkoxy-substituted octadiene.
Abstract translation: 用于丁二烯调聚的方法包括在催化剂促进剂和包含第VIII族过渡金属和三芳基膦配体的烷氧基二聚催化剂的存在下，使1,3-丁二烯和链烷醇反应，其包括一个苯基， 烷氧基取代的和至少一种其它苯基，包括至少一个从磷原子撤出电子的取代基。 该产物包括烷氧基取代的辛二烯，然后可以用它来生产1-辛烯。 该催化剂显示改进的对烷氧基取代的辛二烯的稳定性，活性和选择性。
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公开(公告)号：US08993692B2
公开(公告)日：2015-03-31
申请号：US13700503
申请日：2011-06-29
Applicant: Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, Jr. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
Inventor： Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, Jr. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
IPC: C08F4/649 , C08F2/34 , C08F10/02 , C08F110/02 , C08F210/16
CPC classification number: C08F110/02 , C08F210/16 , C08F4/6494 , C08F2/001 , C08F4/6495 , C08F4/653 , C08F2/34 , C08F2/005 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/17 , C08F2500/20
Abstract: A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
Abstract translation: 一种用于聚合乙烯以制备乙烯基聚合物的方法，包括使乙烯与齐格勒 - 纳塔前催化剂，烷基铝助催化剂和选自脂族，脂环族，取代的脂环族或芳族酯的自限制剂接触，酸酐和酰胺使得 自限制剂在等于或大于120℃的温度下，在不存在自限制剂的情况下将聚合速率降低到不大于聚合速率的40％。
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公开(公告)号：US20110137086A1
公开(公告)日：2011-06-09
申请号：US13002719
申请日：2009-07-22
Applicant: John R. Briggs , Jasson T. Patton , Sonet Vermaire-Louw , Peter M. Margl , Henk Hagen , Daryoosh Beigzadeh
Inventor： John R. Briggs , Jasson T. Patton , Sonet Vermaire-Louw , Peter M. Margl , Henk Hagen , Daryoosh Beigzadeh
CPC classification number: C07C41/06 , C07C1/20 , C07C43/178 , C07C43/15
Abstract: In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C1-C20-hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C1-C20-hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.
Abstract translation: 在用于调聚丁二烯的改进方法中，接触丁二烯和由式ROH（I）表示的有机羟基化合物，其中R是取代或未取代的C 1 -C 20 - 烃基，有机羟基化合物不是甘油，在 存在钯催化剂和由式PAr 3（II）表示的膦配体，其中每个Ar独立地是在至少一个邻位具有氢原子的取代或未取代的芳基，至少两个Ar基团是邻 - 烃氧基取代的芳基。 膦配体共有二（2），三（3），四（4），五（5）或六（6）取代或未取代的C1-C20烃氧基，任选地，任何两个相邻的取代基 Ar基团可以键合形成5-至7-元环。
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公开(公告)号：US07943546B2
公开(公告)日：2011-05-17
申请号：US12434436
申请日：2009-05-01
Applicant: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
Inventor： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC classification number: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
Abstract: A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
Abstract translation: 用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法，所述催化剂组合物包含过渡金属化合物，助催化剂和聚合改性剂，以及由此产生的催化剂组合物和改进的烯烃聚合方法。
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Patent Agency Ranking
公开(公告)号：US08558030B2
公开(公告)日：2013-10-15
申请号：US13002719
申请日：2009-07-22
Applicant: John R. Briggs , Jasson T. Patton , Sonet Vermaire-Louw , Peter M. Margl , Henk Hagen , Daryoosh Beigzadeh
Inventor： John R. Briggs , Jasson T. Patton , Sonet Vermaire-Louw , Peter M. Margl , Henk Hagen , Daryoosh Beigzadeh
IPC: C07C41/06 , C07C43/178 , C07C1/20
CPC classification number: C07C41/06 , C07C1/20 , C07C43/178 , C07C43/15
Abstract: In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C1-C20-hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C1-C20-hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.
Abstract translation: 在用于调聚丁二烯的改进方法中，接触丁二烯和由式ROH（I）表示的有机羟基化合物，其中R是取代或未取代的C 1 -C 20 - 烃基，有机羟基化合物不是甘油，在 存在钯催化剂和由式PAr 3（II）表示的膦配体，其中每个Ar独立地是在至少一个邻位具有氢原子的取代或未取代的芳基，至少两个Ar基团是邻 - 烃氧基取代的芳基。 膦配体共有二（2），三（3），四（4），五（5）或六（6）取代或未取代的C1-C20烃氧基，任选地，任何两个相邻的取代基 Ar基团可以键合形成5-至7-元环。
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公开(公告)号：US08343886B2
公开(公告)日：2013-01-01
申请号：US13081659
申请日：2011-04-07
Applicant: Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
Inventor： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
CPC classification number: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
Abstract: A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and propylene and a polymerization process using the polymerization modifier.
Abstract translation: 包含用于共聚至少一种烯烃单体和丙烯的聚合改性剂和使用聚合改性剂的聚合方法的组合物。
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公开(公告)号：US20110184135A1
公开(公告)日：2011-07-28
申请号：US13081653
申请日：2011-04-07
Applicant: Daryoosh Beigzadeh , Richard E. Campbell, JR. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
Inventor： Daryoosh Beigzadeh , Richard E. Campbell, JR. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
IPC: C08F4/6592 , B01J31/14 , C08F4/52 , C08F4/642
CPC classification number: C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
Abstract: A composition comprising a polymerization modifier for the copolymerization of at least one olefin monomer and 1-octene and a polymerization process using the polymerization modifier.
Abstract translation: 包含用于共聚至少一种烯烃单体和1-辛烯的聚合改性剂和使用聚合改性剂的聚合方法的组合物。
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公开(公告)号：US20080298170A1
公开(公告)日：2008-12-04
申请号：US12114323
申请日：2008-05-02
Applicant: Daryoosh Beigzadeh , Victor A. Atiemo-Obeng , Laura J. Dietsche , David R. Neithamer
Inventor： Daryoosh Beigzadeh , Victor A. Atiemo-Obeng , Laura J. Dietsche , David R. Neithamer
IPC: B01F7/00
CPC classification number: B01F7/00216 , B01F7/001 , B01F7/00141 , B01F7/00583
Abstract: This invention is a stirrer, impeller or stirrer paddle used for mixing small volumes of liquid in a vessel having a small capacity for liquid, said impeller being characterized by an impeller blade connected to the bottom portion of a support, where the blade has an opening extending through the blade from the front to the back surface of the blade said opening extending across the rotational axis of the impeller. The invention is also an apparatus comprising that blade, a method of mixing components using the apparatus and an array of two or more of the apparatuses.
Abstract translation: 本发明是用于在液体容量小的容器中混合少量液体的搅拌器，叶轮或搅拌桨，所述叶轮的特征在于连接到支撑件底部的叶轮叶片，其中叶片具有开口 从刀片的前部延伸到后表面，所述开口延伸穿过叶轮的旋转轴线。 本发明还是一种包括该刀片的装置，使用该装置混合部件的方法和两个或更多个装置的阵列。
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公开(公告)号：US20130131289A1
公开(公告)日：2013-05-23
申请号：US13700503
申请日：2011-06-29
Applicant: Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, JR. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
Inventor： Robert J. Jorgensen , Sean W. Ewart , Richard E. Campbell, JR. , Daryoosh Beigzadeh , Robert D. Froese , Peter M. Margl
IPC: C08F110/02
CPC classification number: C08F110/02 , C08F210/16 , C08F4/6494 , C08F2/001 , C08F4/6495 , C08F4/653 , C08F2/34 , C08F2/005 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/17 , C08F2500/20
Abstract: A process for polymerizing ethylene to produce an ethylene-based polymer including contacting ethylene with a Ziegler-Natta procatalyst, an alkylaluminum cocatalyst and a self limiting agent selected from the group of aliphatic, cycloaliphatic, substituted cycloaliphatic or aromatic esters, anhydrides and amides such that the self limiting agent reduces polymerization rates to no greater than 40% of the polymerization rate in the absence of the self limiting agent at temperatures equal to or greater than 120° C. is provided.
Abstract translation: 一种用于聚合乙烯以制备乙烯基聚合物的方法，包括使乙烯与齐格勒 - 纳塔前催化剂，烷基铝助催化剂和选自脂族，脂环族，取代的脂环族或芳族酯的自限制剂接触，酸酐和酰胺使得 自限制剂在等于或大于120℃的温度下，在不存在自限制剂的情况下将聚合速率降低到不大于聚合速率的40％。
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