Invention Grant
US09045618B2 Liquid stabilizer mixtures 有权
液体稳定剂混合物

  • Patent Title: Liquid stabilizer mixtures
  • Patent Title (中): 液体稳定剂混合物
  • Application No.: US14345998
    Application Date: 2012-09-27
  • Publication No.: US09045618B2
    Publication Date: 2015-06-02
  • Inventor: Jiong YuRoswell Easton King
  • Applicant: BASF SE
  • Applicant Address: DE Ludwigshafen
  • Assignee: BASF SE
  • Current Assignee: BASF SE
  • Current Assignee Address: DE Ludwigshafen
  • Agent Tyler A. Stevenson
  • International Application: PCT/US2012/057501 WO 20120927
  • International Announcement: WO2013/055524 WO 20130418
  • Main IPC: C08K5/134
  • IPC: C08K5/134 C08K5/52
Liquid stabilizer mixtures
Abstract:
The present invention relates to two processes for providing stable liquid blends of a) pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, b) octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and c) tris-(2,4-di-tert-butylphenyl)phosphite. The first process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a), about 2 parts to about 3 parts by weight b) and about 2 parts to about 12 parts by weight c), heating the mixture to 185° C. or higher for a sufficient time to obtain a clear liquid blend of a), b) and c), cooling the liquid blend to a temperature of from 90° C. to 140° C. and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The second process comprises preparing a solid mixture comprising about 2 parts to about 3 parts by weight a) and about 2 parts to about 3 parts by weight b), heating the mixture to 90° C. or higher for a sufficient time to obtain a clear liquid mixture of a) and b), adding about 2 parts to about 12 parts by weight c) thereto to obtain a clear liquid blend of a), b) and c) and maintaining the liquid blend at a temperature of from 90° C. to 140° C. The liquid blends of a), b) and c) are stable at the temperature at which they are maintained for greater than 120 hours.
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