发明授权
- 专利标题: Living coordinative chain transfer polymerization with dynamic counterion exchange
- 专利标题(中): 活性配位链转移聚合与动态抗衡离子交换
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申请号: US13703212申请日: 2011-06-10
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公开(公告)号: US09175103B2公开(公告)日: 2015-11-03
- 发明人: Lawrence R. Sita , Jia Wei , Wei Zhang
- 申请人: Lawrence R. Sita , Jia Wei , Wei Zhang
- 申请人地址: US MD College Park
- 专利权人: University of Maryland, College Park
- 当前专利权人: University of Maryland, College Park
- 当前专利权人地址: US MD College Park
- 代理机构: Sterne, Kessler, Goldstein & Fox PLLC
- 国际申请: PCT/US2011/040025 WO 20110610
- 国际公布: WO2011/156742 WO 20110105
- 主分类号: C08F4/643
- IPC分类号: C08F4/643 ; C08F4/6592 ; C08F210/00 ; C08F210/16 ; C08F4/659
摘要:
Disclosed is a method of producing a polyolefin composition comprising contacting a metal alkyl and a first olefin monomer, then adding a first co-catalyst, a second co-catalyst, a pre-catalyst, and a second olefin monomer. The method allows for the production of a series of copolymers with tunable incorporation ratios of the first olefin monomer. The method also allows for the production of polyolefins of low molecular weights and narrow molecular weight distributions.
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