Invention Grant
US09206266B2 Tridentate pincer ligand supported metal-alkylidyne and metallacycloalkylene complexes for alkyne polymerization
有权
用于炔炔聚合的三齿钳配体负载的金属 - 亚烷基和金属亚环烷基配合物
- Patent Title: Tridentate pincer ligand supported metal-alkylidyne and metallacycloalkylene complexes for alkyne polymerization
- Patent Title (中): 用于炔炔聚合的三齿钳配体负载的金属 - 亚烷基和金属亚环烷基配合物
-
Application No.: US14299449Application Date: 2014-06-09
-
Publication No.: US09206266B2Publication Date: 2015-12-08
- Inventor: Adam Steven Veige , Soumya Sarkar , Kevin Patrick McGowan , Subramaniam Kuppuswamy , Christopher D. Roland
- Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.
- Applicant Address: US FL Gainesville
- Assignee: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.
- Current Assignee: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.
- Current Assignee Address: US FL Gainesville
- Agency: Saliwanchik, Lloyd & Eisenschenk
- Main IPC: C08F4/78
- IPC: C08F4/78 ; C08F38/00 ; C08F4/62
Abstract:
Tridentate pincer ligand supported metal complexes are formed where the complex is a trianionic pincer ligand supported metal-alkylidyne complex or a tetra-anionic pincer-ligand supported metallacycloalkylene complex formed by addition of an alkyne to the trianionic pincer ligand supported metal-alkylidyne complex. The tridentate pincer ligand supported metal complex that includes a group 5-7 transition metal and an OCO trianionic pincer ligand or an alkyne adduct thereof and methods of preparing the complexes are disclosed. The use of the tridentate pincer ligand supported metal complex for the polymerization of alkynes is disclosed, where high molecular weight poly(alkyne)s can be formed in high yield. The poly(alkyne) can be a macrocyclic polymer.
Public/Granted literature
Information query
IPC分类:
