公开(公告)号：US20170022230A1

公开(公告)日：2017-01-26

申请号：US15286780

申请日：2016-10-06

Applicant: University of Florida Research Foundation, Inc.

Inventor： Adam Steven Veige ,  Matthew O'Reilly

IPC: C07F11/00 ,  C07F9/54 ,  C07C215/68

CPC classification number: C07F11/00 ,  C07C213/02 ,  C07C215/50 ,  C07C215/68 ,  C07C215/82 ,  C07F9/5456 ,  C07F11/005

Abstract: Embodiments of the invention are directed to ONO pincer ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are a pair of sp2 hybridized carbons and an sp3 hybridized carbon.

Abstract translation: 本发明的实施方案涉及可以处于三阴离子，质子化或质子化等价形式的ONO钳子配体。 ONO钳子配体可以与含金属的化合物组合以形成包含过渡金属络合物的ONO钳形配体。 通过选择ONO钳子配体结构，可以控制其金属络合物的空间和电子性质。 ONO钳子配体包含被一对三原子包含桥二取代的中心氮原子，其中三个原子是一对sp2杂化碳和sp3杂化碳。

公开(公告)号：US08889879B2

公开(公告)日：2014-11-18

申请号：US13872544

申请日：2013-04-29

Applicant: University of Florida Research Foundation, Inc.

Inventor： Adam Steven Veige ,  Trevor Del Castillo ,  Leslie Justin Murray ,  Xi Yang ,  Andrew R. Powers

IPC: C07F1/12 ,  C07F9/50

CPC classification number: C07F1/12 ,  C07F9/5045

Abstract: Embodiments of the invention are directed to bimetallic substituted triazole compounds and methods to prepare the compounds. The compounds include at least one 1,2,3-triazole that is substituted by two metal ions at the 1 and 4 or 5 positions of the triazole ring. An iClick reaction between a metal acetylide and a metal azide results in the bimetallic substituted triazole ring. Depending on the metal acetylide and the metal azide used, monomeric bimetallic substituted triazole compounds, oligomeric bimetallic triazole compounds, or polymeric bimetallic triazole compounds are formed. Polymeric bimetallic triazole compounds can be linear, branched, ladder, two-dimensional network, or three-dimensional networks.

Abstract translation: 本发明的实施方案涉及双金属取代的三唑化合物和制备化合物的方法。 所述化合物包括在三唑环的1和4或5位被两个金属离子取代的至少一个1,2,3-三唑。 金属乙炔化物和金属叠氮化物之间的iClick反应导致双金属取代的三唑环。 根据金属乙炔化物和所用的金属叠氮化物，形成单体双金属取代的三唑化合物，低聚双金属三唑化合物或聚合双金属三唑化合物。 聚合双金属三唑化合物可以是直链，支链，梯子，二维网络或三维网络。

公开(公告)号：US09464104B2

公开(公告)日：2016-10-11

申请号：US14077822

申请日：2013-11-12

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： Adam Steven Veige ,  Matthew O'Reilly ,  Muhammad Tariq Jan

IPC: C07F11/00 ,  C07C215/50 ,  C07D207/323 ,  C07C215/82 ,  C07C213/02

CPC classification number: C07F11/00 ,  C07C213/02 ,  C07C215/50 ,  C07C215/68 ,  C07C215/82 ,  C07F9/5456 ,  C07F11/005

Abstract: Embodiments of the invention are directed to ONO pincer ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a transition metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the transition metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are three sp2 hybridized carbons or the three atoms are a pair of sp2 hybridized carbons and an sp3 hybridized carbon or silicon.

Abstract translation: 本发明的实施方案涉及可以处于三阴离子，质子化或质子化等价形式的ONO钳子配体。 ONO钳子配体可以与包含过渡金属的化合物组合以形成包含过渡金属络合物的ONO钳形配体。 通过选择ONO钳子配体结构，可以控制其过渡金属络合物的空间和电子性质。 ONO钳子配体包含中心氮原子，其被三对原子包含三个原子的三个sp2杂化的碳原子一起三取代，或者三个原子是一对sp2杂化的碳和一个sp3杂化的碳或硅。

公开(公告)号：US09765102B2

公开(公告)日：2017-09-19

申请号：US15286780

申请日：2016-10-06

Applicant: University of Florida Research Foundation, Inc.

Inventor： Adam Steven Veige ,  Matthew O'Reilly

IPC: C07F11/00 ,  C07C215/68 ,  C07C215/50 ,  C07C215/82 ,  C07C213/02 ,  C07F9/54

CPC classification number: C07F11/00 ,  C07C213/02 ,  C07C215/50 ,  C07C215/68 ,  C07C215/82 ,  C07F9/5456 ,  C07F11/005

Abstract: Embodiments of the invention are directed to ONO pincer ligands that can be in a trianionic, protonated or protonated equivalent form. The ONO pincer ligand can be combined with a metal comprising compound to form an ONO pincer ligand comprising transition metal complex. By choice of the ONO pincer ligand structure, the steric and electronic properties of the metal complexes therefrom can be controlled. The ONO pincer ligands comprise a central nitrogen atom that is disubstituted with a pair of three atom comprising bridges where the three atoms are a pair of sp2 hybridized carbons and an sp3 hybridized carbon.

公开(公告)号：US09206266B2

公开(公告)日：2015-12-08

申请号：US14299449

申请日：2014-06-09

Applicant: UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.

Inventor： Adam Steven Veige ,  Soumya Sarkar ,  Kevin Patrick McGowan ,  Subramaniam Kuppuswamy ,  Christopher D. Roland

IPC: C08F4/78 ,  C08F38/00 ,  C08F4/62

CPC classification number: C08F4/78 ,  C08F4/62082 ,  C08F4/62141 ,  C08F30/08 ,  C08F38/00 ,  C08G61/08 ,  C08G2261/418

Abstract: Tridentate pincer ligand supported metal complexes are formed where the complex is a trianionic pincer ligand supported metal-alkylidyne complex or a tetra-anionic pincer-ligand supported metallacycloalkylene complex formed by addition of an alkyne to the trianionic pincer ligand supported metal-alkylidyne complex. The tridentate pincer ligand supported metal complex that includes a group 5-7 transition metal and an OCO trianionic pincer ligand or an alkyne adduct thereof and methods of preparing the complexes are disclosed. The use of the tridentate pincer ligand supported metal complex for the polymerization of alkynes is disclosed, where high molecular weight poly(alkyne)s can be formed in high yield. The poly(alkyne) can be a macrocyclic polymer.

Abstract translation: 形成三齿夹心配体负载的金属络合物，其中络合物是负载金属 - 亚烷基复合物的三阴离子夹子配体支持的金属 - 亚烷基络合物或通过向三阴离子pincer配体负载的金属 - 亚烷基络合物中加入形成的四阴离子螯合物 - 配体支持的金属亚烷基络合物。 公开了包含5-7族过渡金属和OCO三阴离子螯合配体或其炔加合物的三齿钳配体负载的金属络合物和制备络合物的方法。 公开了三齿钳配体负载的金属络合物用于炔烃聚合的用途，其中可以高产率形成高分子量聚（炔烃）。 聚（炔）可以是大环聚合物。