A transfix surface member for use in aqueous ink jet printer comprises a substrate. A conformance layer is disposed on the substrate layer. A surface layer comprising a siloxane polymer network is on the conformance layer. The siloxane polymer network comprises a plurality of diphenylsiloxane moieties and a plurality of polar moieties, the diphenylsiloxane moieties and polar moieties being bonded to the siloxane polymer network by one or more siloxane linkages. An indirect printing apparatus employing the transfix surface member is also disclosed.