发明授权
- 专利标题: Copper(I) complexes for optoelectronic devices
- 专利标题(中): 铜(I)配合物用于光电器件
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申请号: US14131631申请日: 2012-07-09
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公开(公告)号: US09266906B2公开(公告)日: 2016-02-23
- 发明人: Thomas Baumann , Tobias Grab , Larissa Bergmann
- 申请人: Thomas Baumann , Tobias Grab , Larissa Bergmann
- 申请人地址: DE Eggenstein-Leopoldshafen
- 专利权人: CYNORA GMBH
- 当前专利权人: CYNORA GMBH
- 当前专利权人地址: DE Eggenstein-Leopoldshafen
- 代理机构: Ryan, Mason & Lewis, LLP
- 优先权: EP11173371 20110708; EP11176760 20110805; EP11179112 20110826
- 国际申请: PCT/EP2012/063444 WO 20120709
- 国际公布: WO2013/007707 WO 20130117
- 主分类号: C07F1/08
- IPC分类号: C07F1/08 ; H01L51/56 ; C07F9/50 ; C09K11/06 ; H01L51/00 ; C07F1/00 ; H01L51/50
摘要:
Copper(I) complexes for the emission of light with a structure according to formula A: wherein: M is Cu(I); L-B-L: a neutral, bidentate ligand, Z4-Z7: includes N or the fragment CR, with R=organic group, selected from the group consisting of: hydrogen, halogen or deuterium or groups which are bound via oxygen (—OR′″), nitrogen (—NR′″2), or phosphorous atoms (PR′″2) as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl, trialkylsilyl and triarylsilyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium or lower alkyl groups; X is either CR′″2 or NR′″; Y is either O, S or NR′″; Z8 includes the fragment CR′, with R′=O*R′″, N*R′″2 or P*R′″2, wherein the bond to the Cu atom is carried out via these groups; R″ is a sterically demanding substituent, which inhibits a change in geometry in direction to planarization of the complex in excited state, R′″=organic group which is selected from the group consisting of: hydrogen, halogen or deuterium, as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium, alkyl groups, and further generally known donor and acceptor groups * indicates the atom which receives the complex bond; and # indicates the atom which mediates the bond with the second chemical unit.
公开/授权文献
- US20140235006A1 COPPER(I) COMPLEXES FOR OPTOELECTRONIC DEVICES 公开/授权日:2014-08-21
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