The instant invention provides a polyolefin blend composition suitable for extrusion coating or extrusion lamination applications, and multilayer structure and articles made therefrom. The polyolefin blend composition suitable for extrusion coating or extrusion lamination applications according to the present invention comprises (a) a linear low density polyethylene composition comprising: less than or equal to 100 percent by weight of the units derived from ethylene; less than 35 percent by weight of units derived from one or more ?-olefin comonomers; wherein said polyethylene composition has a density in the range of 0.890 to 0.940 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 2.5 to 4.5, a melt index (I2) in the range of 4 to 30 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of from 2.0 to 3, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition, and a zero shear viscosity ratio (ZSVR) in the range from 1 to 1.2; and (b) less than 50 percent by weight of a low density polyethylene composition having a density in the range of 0.915 to 0.930 g/cm3, a melt index (I2) in the range of 0.1 to 10 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of 6 to 15.