发明授权
US09287553B2 Composite of metal oxide nanoparticles and carbon, method of production thereof, electrode and electrochemical element employing said composite
有权
金属氧化物纳米颗粒和碳的复合物,其制备方法,使用所述复合材料的电极和电化学元件
- 专利标题: Composite of metal oxide nanoparticles and carbon, method of production thereof, electrode and electrochemical element employing said composite
- 专利标题(中): 金属氧化物纳米颗粒和碳的复合物,其制备方法,使用所述复合材料的电极和电化学元件
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申请号: US13638542申请日: 2011-03-31
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公开(公告)号: US09287553B2公开(公告)日: 2016-03-15
- 发明人: Katsuhiko Naoi , Wako Naoi , Shuichi Ishimoto , Kenji Tamamitsu
- 申请人: Katsuhiko Naoi , Wako Naoi , Shuichi Ishimoto , Kenji Tamamitsu
- 申请人地址: JP Tokyo
- 专利权人: NIPPON CHEMI-CON CORPORATION
- 当前专利权人: NIPPON CHEMI-CON CORPORATION
- 当前专利权人地址: JP Tokyo
- 优先权: JP2010-084644 20100331; JP2010-106051 20100504; JP2010-250185 20101108
- 国际申请: PCT/JP2011/001966 WO 20110331
- 国际公布: WO2011/122047 WO 20111006
- 主分类号: H01M4/1391
- IPC分类号: H01M4/1391 ; H01M4/139 ; H01M4/1393 ; H01M4/36 ; H01M4/48 ; H01M4/485 ; H01M4/50 ; H01M4/505 ; H01M4/525 ; B82Y40/00 ; H01M4/131 ; C01B25/45 ; H01G11/36 ; H01G11/46 ; H01M10/0525 ; H01G4/008 ; H01G11/24 ; H01M4/62 ; C01G23/00 ; C01G45/02
摘要:
A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidly heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400° C.-1000° C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.
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