发明授权
- 专利标题: Method and apparatus for producing long carbon nanotubes
- 专利标题(中): 用于生产长碳纳米管的方法和装置
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申请号: US14366366申请日: 2012-11-28
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公开(公告)号: US09315386B2公开(公告)日: 2016-04-19
- 发明人: Vladimir Zalmanovich Mordkovich , Aida Razimovna Karaeva , Maxim Alexandrovich Khaskov , Eduard Borisovich Mitberg
- 申请人: Vladimir Zalmanovich Mordkovich , Aida Razimovna Karaeva , Maxim Alexandrovich Khaskov , Eduard Borisovich Mitberg
- 申请人地址: CY Limassol
- 专利权人: INFRA CARBON LIMITED
- 当前专利权人: INFRA CARBON LIMITED
- 当前专利权人地址: CY Limassol
- 代理机构: Weiner & Burt, P.C.
- 代理商 Irving M. Weiner; Pamela S. Burt
- 优先权: RU2011148461 20111129
- 国际申请: PCT/RU2012/000985 WO 20121128
- 国际公布: WO2013/081499 WO 20130606
- 主分类号: C01B31/02
- IPC分类号: C01B31/02 ; B01J19/24 ; B82Y30/00 ; B82Y40/00
摘要:
The present invention is used to produce long carbon nanotubes used, for example, in automobile and/or aircraft industry. An object of the invention is to obtain bundles of multi-walled and well oriented nanotubes of sufficient length and provide stability of continuous nanotubes producing process. The method comprises introducing a carbon-bearing component, a promoter and a precursor of a carbon nanotube growth catalyst in a carrier gas stream to form a mixture of these components; passing said mixture through the a reactor heated to an operating temperature of 1000° C. to 1200° C. and removing nanotubes formed in the reactor into a product receiver. The mixture is fed in the reactor from the bottom upwards at a linear flow velocity of 50 mm/c to 130 mm/c. When the temperature in the reactor reaches said operating temperature, the linear flow velocity of the mixture is decreased to 4-10 mm/c, and the linear flow velocity is increased to 30-130 mm/c at the outlet of the reactor. The apparatus comprises means for introducing the carbon-bearing component, the promoter and the precursor of the carbon nanotube growth catalyst in the carrier gas stream, a vertical reactor with a working chamber, means for heating the working chamber to the operating temperature, means for delivering the mixture to the working chamber of the reactor and means for removing products from the working chamber. The chamber is made of three successive sections, namely a lower inlet 16 section, a middle 17 section and an upper outlet 18 section and the diameter of the lower section 16 is ⅕ to ⅓ of the diameter of the middle section 17, while the diameter of the upper section 18 is from ¼ to ⅓ of the diameter of the middle section 17.
公开/授权文献
- US20140335009A1 METHOD AND APPARATUS FOR PRODUCING LONG CARBON NANOTUBES 公开/授权日:2014-11-13
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