发明授权
- 专利标题: Process for preparing polyamides
- 专利标题(中): 制备聚酰胺的方法
-
申请号: US13514364申请日: 2010-12-03
-
公开(公告)号: US09315626B2公开(公告)日: 2016-04-19
- 发明人: Faissal-Ali El-Toufaili , Philippe Desbois , Andreas Wollny , Sven Lawrenz , Christian Schmidt
- 申请人: Faissal-Ali El-Toufaili , Philippe Desbois , Andreas Wollny , Sven Lawrenz , Christian Schmidt
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Drinker Biddle & Reath LLP
- 优先权: EP09178358 20091208
- 国际申请: PCT/EP2010/068788 WO 20101203
- 国际公布: WO2011/069892 WO 20110616
- 主分类号: C08G69/24
- IPC分类号: C08G69/24 ; C08G69/26 ; C08G69/28
摘要:
The present invention relates to a process for preparing a polyamide based on dicarboxylic acids and diamines, comprising the following stages: A) providing an aqueous monomer mixture composed of dicarboxylic acids and diamines, where the molar ratio of dicarboxylic acids to diamines is adjusted such that, at the outlet of stage C), there is a molar deficiency of dicarboxylic acids or diamines of 1 to 10 mol %, based on the respective other component, B) transferring the aqueous mixture from stage A) into a continuous evaporator reactor in which diamines and dicarboxylic acids are converted at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, C) transferring the mixture from stage B) into a separator which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar with removal of gaseous components, D) transferring the mixture from stage C) together with diamine or dicarboxylic acid in an amount suitable for compensation for the molar deficiency into a tubular reactor which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, for a residence time in the range from 10 seconds to 30 minutes, E) transferring the mixture from stage D) into an extruder which is operated at a temperature in the range from 150 to 400° C. for a residence time in the range from 10 seconds to 30 minutes with removal of gaseous components through venting orifices.
公开/授权文献
- US20120245308A1 PROCESS FOR PREPARING POLYAMIDES 公开/授权日:2012-09-27
信息查询