A scheduling method and a scheduling apparatus based on physical layer network coding for bidirectional traffic are provided. The method includes setting up paths passing through a node to perform the physical layer network coding of the bidirectional traffic of sessions that pass through the node. The method further includes requesting, from neighboring nodes of the node, information to be used to schedule the sessions for the physical layer network coding. The method further includes scheduling the sessions for the physical layer network coding based on a queue differential of each session that is calculated based on the information, and a rate of each link of each session.