Invention Grant
- Patent Title: High-pressure polymerization process of ethylenically unsaturated monomers in a tubular reactor
- Patent Title (中): 烯属不饱和单体在管式反应器中的高压聚合方法
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Application No.: US15044855Application Date: 2016-02-16
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Publication No.: US09441057B1Publication Date: 2016-09-13
- Inventor: Dieter Littmann , Jurgen Peter Mohrbutter , Giulia Mei , Andre-Armand Finette , Sven Georg Wolfram , Michael Deuerling , Danir Khayrullin , Georg Groos , Christoph Wolf
- Applicant: Basell Polyolefine GmbH
- Applicant Address: DE Wesseling
- Assignee: Basell Polyolefine GmbH
- Current Assignee: Basell Polyolefine GmbH
- Current Assignee Address: DE Wesseling
- Priority: EP15178042 20150723
- Main IPC: C08F2/01
- IPC: C08F2/01 ; C08F2/34 ; C08F2/38 ; C08F110/02 ; C08J5/18

Abstract:
The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.
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