Embodiments provided herein describe solid-state lithium batteries and methods for forming such batteries. A first current collector is provided. A first layer is formed above the first current collector. The first layer includes lithium and cobalt. The first layer is annealed. A second layer is formed above the annealed first layer. The second layer includes lithium and cobalt, and the annealed first layer and the second layer jointly form a first electrode. An electrolyte is formed above the first electrode. A second electrode is formed above the electrolyte. A second current collector is formed above the second electrode.